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US 11,987,659 B2Granted
Hydrogenation reaction catalyst and preparation method therefor
AssigneeHanwha Solutions Corporation
InventorsBong Sik Jeon, Wan Jae Myeong, Woo Jin Park, Eui Geun Jung
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Abstract
Provided are a hydrogenation reaction catalyst and a preparation method therefor, and more particularly, to a hydrogenation reaction catalyst including sulfur as a promoter, thereby selectively hydrogenating an olefin by changing a relative hydrogenation rate of the olefin and an aromatic group during a hydrogenation reaction of an unsaturated hydrocarbon compound containing an aromatic group, and a preparation method therefor.
Claims9
A hydrogenation reaction catalyst for petroleum resin;
- comprising nickel, a promoter, and a carrier,
- wherein the promoter comprises copper and sulfur,
- the carrier is at least one selected from the group consisting of silica and alumina,
- the nickel has an average crystal size of 1 nm to 10 nm and the hydrogenation reaction catalyst has an average particle size of 1 μm to 20 μm,
- a content of the nickel is in a range of 62 parts by weight to 65 parts by weight based on 100 parts by weight of the hydrogenation reaction catalyst,
- a content of the copper is in a range of 0.8 parts by weight to 1 parts by weight based on 100 parts by weight of the hydrogenation reaction catalyst,
- a mole ratio of the sulfur to the nickel is in a range of 0.02:1 to 0.2:1,
- a content of the sulfur is in a range of 2.2 parts by weight to 2.9 parts by weight based on 100 parts by weight of the hydrogenation reaction catalyst,
- the catalyst is to selectively hydrogenate an olefin by changing a relative hydrogenation rate of the olefin and an aromatic group during a hydrogenation reaction of an unsaturated hydrocarbon compound containing the aromatic group of the petroleum resin, and
- the aromatic/olefin hydrogenation ratio is 0.3-0.8.
7 more elements
Dependencies are inferred from the claim text.