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US 11,970,671 B2Granted
Detergent systems for oxidation resistance in lubricants
AssigneeAfton Chemical Corporation
InventorsPaul Ransom, Latifa Hamdani
Life of this patent
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Abstract
The present disclosure relates to lubricating compositions having a stable viscosity upon oxidization through select amounts and relationships of detergent metals and soap contents.
Claims17
A lubricating composition comprising:
- one or more base oils of lubricating viscosity;
- sulfurized additives providing at least about 1,500 ppm of sulfur to the lubricating composition;
- one or more boronated dispersants providing about 40 ppm to about 500 ppm boron to the lubricating composition;
- a detergent system providing about 0.2 to about 1.0 weight percent soap content to the lubricating composition and providing magnesium, sodium, and calcium, wherein the detergent system provides greater than about 90 ppm of sodium and no more than about 1,000 ppm of magnesium to the lubricating composition, and wherein the detergent system has a weight ratio of sodium-to-magnesium of about 0.4 to 2.0, and a weight ratio of sulfur-to-sodium of about 12 or less;
- wherein the lubricating composition is contaminated with up to about 30 weight percent of biodiesel fuel and wherein the lubricating composition exhibits viscosity stability upon oxidization when tested pursuant to GFC Lu-43-A-11;
- and
- wherein the lubricating composition includes about 90 ppm to about 1,000 ppm of sodium, about 500 ppm to about 2,000 ppm of calcium, about 100 to about 1,000 ppm of magnesium, about 1,500 to about 4,000 ppm of sulfur, and a weight ratio of calcium-to-magnesium of about 0.5 to about 2.5.
4 more elements
A method of maintaining a stable viscosity in a lubricating composition upon oxidization, the method comprising:
- performing an oxidization test pursuant to GFC Lu-43-A-11 on a lubricating composition;
- the lubricating composition including one or more base oils of lubricating viscosity, sulfurized additives providing at least about 1,500 ppm sulfur, one or more boronated dispersants providing about 40 ppm to about 500 ppm of boron, and a detergent system providing about 0.2 to about 1.0 weight percent soap to the lubricating composition and providing magnesium, sodium, and calcium, wherein the detergent system provides greater than about 90 ppm of sodium and no more than about 1,000 ppm of magnesium to the lubricating composition, and wherein the detergent system has a weight ratio of sodium-to-magnesium of about 0.4 to 2.0, and a weight ratio of sulfur-to-sodium of about 12 or less;
- wherein the lubricating composition exhibits a viscosity increase upon oxidization after 144 hours of no greater than about 150 percent when tested pursuant to GFC Lu-43-A-11;
- and
- wherein the lubricating composition includes about 90 ppm to about 1,000 ppm of sodium, about 500 ppm to about 2,000 ppm of calcium, about 100 to about 1,000 ppm of magnesium, about 1,500 to about 4,000 ppm of sulfur, and a weight ratio of calcium-to-magnesium of about 0.5 to about 2.5.
2 more elements
Dependencies are inferred from the claim text.