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US 11,964,933 B2Granted
Fluorinated aromatic compounds
AssigneeMerck Patent GmbH
InventorsConstanze Brocke, Dmitry Ushakov, Carsten Fritzsch, Dagmar Klass
Life of this patent
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Abstract
The present invention relates to aromatic isothiocyanates of formula U as defined in claim 1, to liquid-crystalline media comprising one or more compounds of formula U and to high-frequency components comprising these media, especially microwave components for high-frequency devices, such as devices for shifting the phase of microwaves, tunable filters, tunable metamaterial structures, and electronic beam steering antennas, e.g. phased array antennas.
Claims20
A compound of formula U
- in which
- RU denotes H, alkyl or alkoxy having 1 to 12 C atoms, or alkenyl,
- alkenyloxy or alkoxyalkyl having 2 to 12 C atoms, in which one or more CH2—groups may be replaced by
- or a group RP,
- RP denotes halogen, CN, NCS, RF, RF—O— or RF—S—, wherein
- RF denotes fluorinated alkyl having 1 to 9 C atoms or fluorinated alkenyl having 2 to 9 C atoms,
- ZU1, ZU2, ZU3 identically or differently, denote —CH═CH—, —CF═CF—, —CH═CF—, —CF═CH—, —C≡C— or a single bond,
- X1, X2 identically or differently, denote H, Cl, F, CH3 or C2H5,
- Y1, Y2, Y3, Y4 identically or differently, denote H, F, Cl, or straight chain alkyl, or alkoxy, each having 1 to 12 C atoms or straight chain alkenyl or alkenyloxy, each having 2 to 12 C atoms or branched or cyclic alkyl, alkenyl, alkoxy or alkenyloxy, each having 3 to 12 C atoms, where at least one of Y1, Y2, Y3 and Y4 is different from F,
- s is 0, 1 or 2,
- t is 0, 1 or 2, and
- s+t is 0, 1 or 2,
- identically or differently, denote a radical selected from the following groups:
- a) the group consisting of 1,4-phenylene, 1,4-naphthylene, and 2,6-naphthylene, in which one or two CH groups may be replaced by N and in which one or more H atoms may be replaced by L,
- b) the group consisting of trans-1,4-cyclohexylene, 1,4-cyclohexenylene, bicyclo[1.1.1]pentane-1,3-diyl, 4,4″-bicyclohexylene, bicyclo[2.2.2]octane-1,4-diyl, spiro[3.3]heptane-2,6-diyl, in which one or more non-adjacent CH2 groups may be replaced by —O— and/or —S— and in which one or more H atoms may be replaced by F, and
- c) the group consisting of thiophene-2,5-diyl, thieno[3,2-b]thiophene-2,5-diyl, selenophene-2,5-diyl, each of which may also be mono- or polysubstituted by L,
- L on each occurrence, identically or differently, denotes F, Cl, CN, SCN, SF5 or straight-chain, in each case optionally fluorinated, alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy having 1 to 12 C atoms or branched, in each case optionally fluorinated, alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy having 3 to 12 C atoms.
14 more elements
Dependencies are inferred from the claim text.