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US 11,964,932 B2Granted
Tricyclodecane dimethanol composition and preparation method of the same
AssigneeSK Chemicals Co., Ltd.
InventorsHee Il Chae, Ju-Sik Kang, Jeong Ho Park, Song Lee, Yu Mi Chang
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Abstract
Provided are a tricyclodecane dimethanol composition, in which a ratio of structural isomers is controlled, and a preparation method thereof.
Claims7
A method of preparing a tricyclodecane dimethanol composition, the method comprising the steps of:
- performing a two-step hydroformylation reaction by:
- a) adding dropwise dicyclopentadiene at a temperature of 75° C. to 85° C. while maintaining a mixed gas of hydrogen and carbon monoxide at a pressure 20 bar to 150 bar in the presence of a catalyst composition including a rhodium-containing catalyst compound and 5 moles to 200 moles of an organophosphorus compound per 1 mole of rhodium, and a dienophile to form a reaction mixture;
- and
- b) after the dropwise addition of dicyclopentadiene is finished, further reacting the reaction mixture while heating the reaction mixture to 130° C. and maintaining the pressure of the CO/H2 mixed gas;
- wherein the method further comprises the steps of:
- performing a hydrogenation reaction of tricyclodecane dialdehyde obtained by the two-step hydroformylation reaction in the presence of a hydrogenation catalyst,
- wherein the tricyclodecane dimethanol composition includes 20 parts by weight to 35 parts by weight of a first structural isomer represented by the following Formula 1-1, 27 parts by weight to 42 parts by weight of a second structural isomer represented by the following Formula 1-2, and 27 parts by weight to 42 parts by weight of a third structural isomer represented by the following Formula 1-3, based on 100 parts by weight of the composition:
4 more elements
Dependencies are inferred from the claim text.