Stretchable supercapacitors with vertically-aligned embedded carbon nanotubes
AssigneeThe Trustees of the Stevens Institute of Technology
InventorsRunzhi Zhang, Junjun Ding, Eui-Hyeok Yang
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Abstract
Flexible and stretchable supercapacitors are made using carbon nanostructures produced by providing a first composite structure which includes a temporary substrate and an array of carbon nanotubes arranged in a stack on a surface of the temporary substrate such that the stack of carbon nanotubes is oriented generally perpendicular to the surface of the temporary substrate, which may include silicon dioxide. The stack of carbon nanotubes is transferred from the temporary substrate to another substrate, which includes a curable polymer, thereby forming another composite structure comprising the stack of carbon nanotubes and the cured polymer.
Claims19
A method of fabricating a flexible and stretchable supercapacitor, comprising the steps of:
- providing a first composite structure which includes a first substrate and an array of carbon nanotubes arranged on a surface of said first substrate such that said array of carbon nanotubes is oriented generally perpendicular to said surface of said first substrate and such that each of said carbon nanotubes has a first end removably embedded in said first substrate and a second end distal to said first substrate;
- providing a second substrate which includes a curable precursor of a polymer selected to have viscoelastic properties;
- providing said second substrate with a curing agent for said precursor;
- partially curing said precursor of said second substrate such that said second substrate includes a partially cured polymer;
- placing said array of carbon nanotubes into contact with said second substrate, while said array of carbon nanotubes is still arranged on said surface of said first substrate, such that said second end of each of said carbon nanotubes is partially embedded in said partially cured polymer of said second substrate before said partially cured polymer is fully cured and such that said partially cured polymer infiltrates between said carbon nanotubes of said array of carbon nanotubes;
- fully curing said partially cured polymer while said second end of each of said carbon nanotubes is partially embedded therein, thereby forming a fully cured polymer that adheres to said second ends of said carbon nanotubes of said array of carbon nanotubes and thereby also forming a second composite structure in the form of a laminate which includes said first substrate, said second substrate and said array of carbon nanotubes between said first and second substrates;
- delaminating said second composite structure by peeling said first substrate away from said array of carbon nanotubes to thereby remove said first ends of said carbon nanotubes from said first substrate and to thereby form a third composite structure which includes said array of carbon nanotubes and said second substrate, but not said first substrate, said third composite structure including said first ends of said carbon nanotubes;
- and
- incorporating said third composite structure into an electrode adapted for use in a flexible supercapacitor.
Dependencies are inferred from the claim text.