Plasticizer migration-resistant, UV-curable hotmelt adhesive for graphics films and labels made of plasticized PVC
AssigneeBASF SE
InventorsDirk Wulff, Ulrike Licht, Thomas Christ, Matthias Gerst
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Abstract
Plasticizer migration-resistant, UV-curable hotmelt adhesive for graphics films and labels made of plasticized PVC Described here is a UV-curable hotmelt adhesive largely resistant to plasticizer migration and comprising a UV-crosslinkable poly(meth)acrylate formed from methyl acrylate, C4-18 alkyl (meth)acrylate, monomer with acid groups, copolymerized photoinitiator and optionally further monomers. The hotmelt adhesive further comprises an aliphatic polyester polymer. The use of the hotmelt adhesive on graphics films and self-adhesive labels made of plasticized PVC is also described.
Claims8
A UV-curable hotmelt adhesive, comprising:
- (a) a UV-crosslinkable poly(meth)acrylate formed from
- (i) 25% to 60% by weight of methyl acrylate,
- (ii) 35% to 60% by weight of an alkyl (meth)acrylate comprising 4 to 8 carbon atoms in the alkyl group,
- (iii) 1% to 10% by weight of an ethylenically unsaturated monomer comprising an acid group,
- (iv) 0.2% to 5% by weight of an ethylenically unsaturated copolymerizable photoinitiator monomer and
- (v) 0% to 25% by weight of a further monomer distinct from (i) to (iv) and
- (b) an aliphatic polyester polymer which at 20° C. has a dynamic viscosity of 500 to 20,000 mPa s in an amount of 1% to 20% by weight, wherein the aliphatic polyester polymer is formed from an aliphatic dicarboxylic acid comprising 3 to 10 carbon atoms and an alkanediol comprising 2 to 10 carbon atoms, and
- wherein a plasticized polyvinyl chloride (PVC) film coated with the UV-curable hotmelt adhesive exhibits a 180 degree peel strength of >10 N/25 mm after storage for 3 days at 70° C. and 50% relative humidity;
- and wherein the plasticized polyvinyl chloride (PVC) film coated with the UV-curable hotmelt adhesive exhibits a shear strength value of >15 h after storage for 3 days at 70° C. and 50% relative humidity.
Dependencies are inferred from the claim text.