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US 11,958,056 B2Granted
Upgraded coal
AssigneeEnergy & Environmental Research Center Foundation
InventorsAlexander Azenkeng, Jason Laumb
Life of this patent
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Abstract
Upgraded coal, method of forming the same, and graphene films and quantum dots made therefrom. A method of upgrading coal includes cleaning coal to form a cleaned coal residue. The method also includes (A) reacting the cleaned coal residue with an oxidizable inorganic metallic agent, or (B) reacting the cleaned coal residue with a reducing agent, or a combination thereof, to form the upgraded coal.
Claims19
A method of upgrading coal, the method comprising:
- cleaning coal to form a cleaned coal residue;
- and
- at least one of
- reacting the cleaned coal residue with an oxidizable inorganic metallic agent, and
- reacting the cleaned coal residue with a reducing agent,
- to form the upgraded coal, wherein the upgraded coal has a lower oxygen concentration as compared to the naturally-sourced coal used to form the upgraded coal.
3 more elements
A method of upgrading coal, the method comprising:
- cleaning coal having a largest dimension of 25 mm or less using a strong mineral acid at a temperature of 30° C. to 100° C. to form a cleaned coal residue;
- and
- at least one of
- reacting the cleaned coal residue at 100° C. to 500° C. under an inert gas with an oxidizable inorganic metallic agent comprising iron (II) sulfate heptahydrate (FeSO4·7H2O), iron (II) chloride tetrahydrate (FeCl·4H2O), or a combination thereof, and
- reacting the cleaned coal residue at 0° C. to 50° C. in an organic solvent with a reducing agent comprising lithium aluminum hydride (LAH), sodium borohydride (NAH), or a combination thereof,
- to form the upgraded coal;
- wherein
- the upgraded coal has a lower ash content, as compared to the coal used to form the upgraded coal, and
- the upgraded coal has a lower oxygen concentration and a higher carbon concentration, as compared to the naturally-sourced coal used to form the upgraded coal.
6 more elements
Dependencies are inferred from the claim text.