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US 11,952,486 B2Granted
Thermoplastic elastomer compounds exhibiting retained clarity and improved surface structure
AssigneeAvient Corporation
InventorsLiang Xu, Christopher Engel
Life of this patent
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Abstract
Surface structure modification is achieved for an acrylate block copolymer thermoplastic elastomer by the addition of an organo-functional polydimethyl siloxane but also without loss of clarity.
Claims12
A thermoplastic elastomer compound, comprising:
- (a) polymethylmethacrylate-polybutyl acrylate-polymethylmethacrylate triblock copolymer,
- (b) a hydroxy functional polydimethylsiloxane comprising dihydroxypolydimethylpolysiloxane, and
- (c) a mold release agent;
- wherein the polymethylmethacrylate-polybutyl acrylate-polymethylmethacrylate triblock copolymer forms a polymer matrix and the hydroxy functional polydimethylsiloxane is incorporated within the polymer matrix by mixing the hydroxy functional polydimethylsiloxane and the polymethylmethacrylate-polybutyl acrylate-polymethylmethacrylate triblock copolymer at a temperature sufficient to melt the polymethylmethacrylate-polybutyl acrylate-polymethylmethacrylate triblock copolymer,
- the hydroxy functionalized polydimethylsiloxane is present in the compound at 0.1 to 0.2 parts per one hundred parts of polymethylmethacrylate-polybutyl acrylate-polymethylmethacrylate triblock copolymer,
- wherein the mold release agent is present in the compound at 0.05 to 0.2 parts per one hundred parts of polymethylmethacrylate-polybutyl acrylate-polymethylmethacrylate triblock copolymer;
- polymethylmethacrylate-polybutyl acrylate-polymethylmethacrylate triblock copolymer includes a first polymethylmethacrylate-polybutyl acrylate-polymethylmethacrylate triblock copolymer that has a Shore A hardness of 62 and a second polymethylmethacrylate-polybutyl acrylate-polymethylmethacrylate triblock copolymer that has a Shore A hardness of 96;
- the compound includes 60 PHR to 75 PHR of the first polymethylmethacrylate-polybutyl acrylate-polymethylmethacrylate triblock copolymer and the compound includes 25 PHR to 40 PHR of the second polymethylmethacrylate-polybutyl acrylate-polymethylmethacrylate triblock copolymer;
- and
- the compound has a haze of less than about 10% when tested using ASTM D1003 and a kinetic coefficient of friction of less than about 0.65 when tested using ASTM D1894.
7 more elements
Dependencies are inferred from the claim text.