Binder compound and method for preparing same
AssigneeContemporary Amperex Technology Co., Limited
InventorsJianghui Lin, Yanjie Zhao, Xing Li, Haizu Jin
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Abstract
The present application relates to a binder compound of formula (I), a method for preparing the same, and an electrode sheet comprising the same. In formula (I), R1, R2, and R3 each independently represents an unsubstituted or substituted linear or branched alkyl with 1-6 carbon atoms, or an unsubstituted or substituted aryl with 6-20 carbon atoms; R4 represents —COOM; R5 represents a bridging oxo or bridging imino; each M independently represents one of Li, Na, K, Rb, and Cs; Z represents a linear or branched alkylene with 1-6 carbon atoms; m is an integer selected from 7,600 to 47,000; n is an integer selected from 1,520 to 94,000; and m/n=0.1-10.
Claims17
A binder compound of formula (I):
- wherein
- R1, R2, and R3 each independently represents an unsubstituted or substituted linear or branched alkyl with 1-6 carbon atoms, or an unsubstituted or substituted aryl with 6-20 carbon atoms;
- R4 represents —COOM;
- R5 represents a bridging oxo or bridging imino;
- each M independently represents one of Li, Na, K, Rb, and Cs;
- Z represents a linear or branched alkylene with 1-6 carbon atoms;
- m is an integer selected from 7,600 to 47,000;
- n is an integer selected from 1,520 to 94,000;
- and
- m/n=0.1-10.
A method for preparing a binder compound of formula (I),
- wherein
- R1, R2, and R3 each independently represents an unsubstituted or substituted linear or branched alkyl with 1-6 carbon atoms, or an unsubstituted or substituted aryl with 6-20 carbon atoms;
- R4 represents —COOM,
- R5 represents a bridging oxo or bridging imino;
- each M independently represents one of Li, Na, K, Rb, and Cs;
- Z represents a linear or branched alkylene with 1-6 carbon atoms;
- m is an integer selected from 7,600 to 47,000;
- n is an integer selected from 1,520 to 94,000;
- and
- m/n=0.1-10;
- the method comprising following steps:
- (i) allowing a polymerization reaction of a vinylidene fluoride monomer in the presence of a chain transfer agent of formula (II) to obtain a polymer of formula (III):
- wherein R1, R3, Z, and m are defined as above respectively;
- and
- optionally, the chain transfer agent of formula (II) is 4-cyano-4-thioylthiopropylsulfanyl pentanoic acid;
- (ii) allowing a polymerization reaction between a glucose acrylic acid derivative of formula (IV) and polyvinylidene fluoride of formula (III) to obtain a polymer of formula (I′):
- wherein R1, R2, R3, Z, m, n, and m/n are as defined above respectively,
- R5 represents a bridging oxo or bridging imino, and
- R6 represents acetyl;
- and (iii) reacting the polymer obtained in the step (ii) with an alkali metal alkoxide R7OM to obtain the binder compound of formula (I):
- wherein R7 is selected from a linear or branched alkyl with 1-6 carbon atoms.
Dependencies are inferred from the claim text.