Defoaming formulations containing organopolysiloxanes

A defoamer formulation, comprising:

• (1) organopolysiloxane(s) containing per molecule at least one structural unit of formula
• O1/2R2Si—Y—SiRO2/2 (I)
• and at least 2 units of formula
• R1R2 SiO1/2 (II)
• and units of general formula
• R2SiO2/2 (III),
• wherein
• R each is identical or different and represents a monovalent SiC-bonded hydrocarbon radical having 1 to 30 carbon atoms which may contain one or more nonadjacent oxygen atoms and which is free from aliphatic carbon-carbon multiple bonds and
• R1 each is R or an alkenyl radical having 2 to 30 carbon atoms, wherein at least one alkenyl radical per molecule is present,
• Y each individually represents a divalent hydrocarbon radical having 2 to 30 carbon atoms, with the proviso that the organopolysiloxane contains a structural element of formula
• R2Y2SiO—(SiR2O)x1—SiRY1O—(SiR2O)x2—SiR2R1 (IV),
• wherein
• R and R1 are as defined above,
• Y1 each individually represents a divalent hydrocarbon radical having 2 to 30 carbon atoms which is bonded to a group having the formula SiR2O1/2,
• Y2 each individually represents a divalent hydrocarbon radical having 2 to 30 carbon atoms which is bonded to a group having the formula SiRO2/2, and
• x1 and x2 is 0 or a positive integer,
• with the proviso that the sum of x1+x2 is x,
• wherein x is on average more than 5, and less than 100,
• (2) fillers,
• (3) organopolysiloxane resin(s) composed of units of formula
• R2e(R3O)fSiO(4-e-f)/2 (V),
• wherein
• R2 each is identical or different and represents a hydrogen atom or a monovalent, optionally substituted, SiC-bonded hydrocarbon radical having 1 to 30 carbon atoms,
• R3 each is identical or different and represents a hydrogen atom or a monovalent, optionally substituted hydrocarbon radical having 1 to 4 carbon atoms,
• e is 0, 1, 2 or 3 and
• f is 0, 1, 2, or 3,
• with the proviso that the sum of e+f is not more than 3 and that the sum of e+f is 2 in less than 50% of all units of formula (V) in the organopolysiloxane resin,
• (4) silanol-containing organopolysiloxane(s) of the formula
• XSiR42O—(SiR42O)n—SiR42X (VI)
• wherein
• R4 each is identical or different and represents a monovalent SiC-bonded hydrocarbon radical having 1 to 30 carbon atoms, which may contain one or more nonadjacent oxygen atoms, and
• X each is a hydrogen atom, an optionally substituted C1-C18-hydrocarbon radical, a C1-C18-alkoxy group or a hydroxyl group —OH,
• n has integral values between 0 and 1000,
• with the proviso that on average 30 to 60 mol %, of the groups X correspond to hydroxyl groups —OH,
• wherein the silanol-containing organopolysiloxanes may also contain small proportions of branchings, as T units (R4SiO3/2) and/or Q units (SiO2), wherein small proportions signify 0 to 1 mol %, based on the sum of all siloxane units in the organopolysiloxane, and
• (5) at least one inorganic or organic acid.