Narrow band emitting SiAION phosphor
AssigneeLumileds LLC
InventorsPeter Josef Schmidt, Philipp-Jean Strobel, Volker Weiler, Andreas Tücks
Life of this patent
Estimating the term…
Abstract
This specification discloses methods of enhancing the stability and performance of Eu2+ doped narrow band red emitting phosphors. In one embodiment the resulting phosphor compositions are characterized by crystallizing in ordered structure variants of the UCr4C4 crystal structure type and having a composition of AE1−xLi3−2yAl1+y−zSizO4−4y−zN4y+z:Eux (AE=Ca, Sr, Ba, or a combination thereof, 0<x<0.04, 0≤y<1, 0<z<0.05, y+z≤1). It is believed that the formal substitution (Al,O)+ by (Si,N)+ reduces the concentration of unwanted Eu3+ and thus enhances properties of the phosphor such as stability and conversion efficiency.
Claims20
A luminescent composition of matter characterized by the formula:
- AE1−xLi3−2yAl1+2y−zSizO4−4y−zN4y+z:Eux;
- AE=Ca,Sr,Ba, or a combination thereof;
- 0<x<0.04;
- 0.4<y<0.6;
- and
- 0<z<0.05,
- the luminescent composition of matter having a tetragonal crystal structure.
Dependencies are inferred from the claim text.