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US 11,920,074 B2Granted
Liquid crystal medium
AssigneeMerck Patent GmbH
InventorsKaja Christina Deing, Sven Christian Laut, Monika Bauer, Sebastian Hofmeyer, Kristin Weiss
Life of this patent
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Abstract
The present invention relates to a liquid crystal (LC) medium comprising a compound of formula I and one or more compounds selected from the group of compounds of the formulae IIA, IIB, IIC and IID, as defined in claim 1, and to the use of the LC medium for optical, electro-optical and electronic purposes, in particular in LC displays, especially in IPS, FFS, VA or PS-VA displays.
Claims19
A liquid crystal medium comprising one or more compounds selected from formulae I-1 and I-2
- in which
- RL1 denotes H, or a straight chain alkyl or alkoxy radical having 1 to 15 C atoms or branched alkyl or alkoxy radical having 3 to 15 C atoms, where one or more CH2 groups in these radicals may each be replaced, independently of one another, by
- —C═C—, —CF2O—, —OCF2—, —CH═CH—, —O—, —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which, in addition, one or more H atoms may each be replaced by halogen,
- and
- one or more compounds selected from the group of compounds of the formulae IIA, IIB, IIC and IID,
- in which
- R2A, R2B, R2C
- and R2D each, independently of one another, denote H, or an alkyl radical having 1 to 15 C atoms or an alkenyl radical having 2 to 15 C atoms which, in each case, is unsubstituted, monosubstituted by CN or CF3 or at least monosubstituted by halogen, where, in addition, one or more CH2 groups in these radicals may each be replaced by —O—, —S—,
- —C≡C—, —CF2O—, —OCF2—, —OC—O— or —O—CO— in such a way that O atoms are not linked directly to one another,
- L1 to L4 each, independently of one another, denote F, Cl, CF3 or CHF2,
- Y denotes H, F, Cl, CF3, CHF2 or CH3,
- Z2, Z2B and Z2D each, independently of one another, denote a single bond, —CH2CH2—, —CH═CH—, —CF2O—, —OCF2—, —CH2O—, —OCH2—, —COO—, —OCO—, —C2F4—, —CF═CF— or —CH═CHCH2O—,
- p denotes 0, 1 or 2,
- q denotes 0 or 1, and
- v denotes 1, 2, 3, 4, 5, or 6,
- wherein said medium has a negative dielectric anisotropy,
- wherein the total concentration of compounds of formula I-1 and I-2 in said medium is 0.5% to 2%,
- wherein the medium further comprises one or more compounds of formula III
- in which
- R11 and R12 each, independently of one another, denote H, an alkyl or alkoxy radical having 1 to 15 C atoms, where one or more CH2 groups in these radicals may each be replaced, independently of one another, by
- —C≡C—, —CF2O—, —OCF2—, —CH═CH—, by —O—, —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which, in addition, one or more H atoms may each be replaced by halogen,
- A1 on each occurrence independently denotes
- a) a 1,4-cyclohexenylene or 1,4-cyclohexylene radical, in which one or two non-adjacent CH2 groups may each be replaced by —O— or —S—,
- b) a 1,4-phenylene radical, in which one or two CH groups may each be replaced by N, or
- c) a radical from the group spiro[3.3]heptane-2,6-diyl, 1,4-bicyclo[2.2.2]octylene, naphthalene-2,6-diyl, decahydronaphthalene-2,6-diyl, 1,2,3,4-tetrahydronaphthalene-2,6-diyl, phenanthrene-2,7-diyl and fluorene-2,7-diyl,
- where the radicals a), b) and c) may be mono- or polysubstituted by halogen atoms,
- n is 0, 1 or 2,
- Z1 on each occurrence independently denotes —CO—O—, —O—CO—, —CF2O—, —OCF2—, —CH2O—, —OCH2—, —CH2—, —CH2CH2—, —(CH2)4—, —CH═CH—CH2O—, —C2F4—, —CH2CF2—, —CF2CH2—, —CF═CF—, —CH═CF—, —CF═CH—, —CH═CH—, —C≡C— or a single bond, and
- L11 and L12 each, independently of one another, denote H, F, Cl, CF3 or CHF2, and
- W denotes S, and
- wherein the mixtures X-1 and X-2 having the following compositions
- Mixture X-1:
- 8%
- 20%
- 10.5%
- 2.0%
- 0.5%
- 11.0%
- 7.5%
- 1.0%
- 10.5%
- 15.5%
- 3.5%
- 10.0%
- Σ
- 100.0%
- Mixture X-2
- 2.0%
- 4.0%
- 37.0%
- 3.0%
- 14.5%
- 11.5%
- 3.0%
- 10.0%
- 14.0%
- 1.0%
- Σ
- 100.0%
- are excluded.
57 more elements
Dependencies are inferred from the claim text.