Process for producing ultrahigh molecular weight polymer in powder form
AssigneeIndian Oil Corporation Limited
InventorsSukhdeep Kaur, Gurmeet Singh, Gurpreet Singh Kapur, Sankara Sri Venkata Ramakumar
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Abstract
The present invention relates to a process for producing ultrahigh molecular weight polymer in powder form which is highly efficient drag reducing polymer. The process consists of polymerizing using titanium halide-based catalyst, co-catalyst, optionally a solvent, and monomer to a polymerization reactor, having stirring device and inlet charging and discharge outlet. The resulting ultrahigh molecular weight drag reducing polymers is free flowing, having intrinsic viscosity >10 dL/g. The process reduces polymerization time, temperature, and achieves high conversion, i.e., >90%.
Claims4
A process for preparing an ultra-high molecular weight drag reducing polymer, the process comprising:
- a. adding a titanium halide based catalyst, wherein the titanium halide based catalyst is supported on a magnesium chloride matrix with/without an internal donor, or unsupported with/without an internal donor;
- b. adding a co-catalyst, wherein the co-catalyst is an organoaluminum compound;
- and
- c. preparing a polymerization mixture comprising the titanium halide based catalyst, the co-catalyst and monomers, wherein the monomers are alpha-olefins with carbon chains having at least four carbons in a polymerization reactor;
- d. continuously stirring the polymerization mixture for a residence time ranging from 12 to 24 hours at a temperature of approximately 10° C. and regulating the stirring depending upon a viscosity of the polymerization mixture to obtain the ultra-high molecular weight drag reducing polymer as a free-flowing powder having an intrinsic viscosity a range of 21 dL/g to 35 dL/g and achieving conversion of at least 90%;
- wherein the polymerization is a bulk polymerization and is carried under inert and oxygen free conditions, at a pressure of 0.5 bar.
Dependencies are inferred from the claim text.