# US 11,908,626 B2 · Multilayer ceramic electronic component and method of manufacturing the same

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- Number: US 11,908,626 B2
- Document ID: US11908626B2
- Status: Granted
- Kind: B2
- Application number: 17/372,828
- Filed: 2021-07-12
- Published: 2022-03-24
- Granted: 2024-02-20
- Earliest claimed: 2020-09-22
- Assignees: Samsung Electro-Mechanics Co., Ltd.
- Applicants: Samsung Electro-Mechanics Co., Ltd.
- Inventors: Jung Eun Noh; Ji Hyuk Lim; Jong Yun Kim; Eun Jung Lee
- Web page: https://patentgrep.com/patent/US11908626B2

## CPC

- H01G 4/30: Stacked capacitors (H01G4/33 takes precedence)
- B32B 18/00: Layered products essentially comprising ceramics, e.g. refractory products
- C04B 35/468: based on barium titanates
- H01G 2/06: specially adapted for mounting on a printed-circuit support
- H01G 2/065: {for surface mounting, e.g. chip capacitors}
- H01G 4/008: Selection of materials
- H01G 4/012: Form of non-self-supporting electrodes
- H01G 4/1218: {based on titanium oxides or titanates (H01G4/1245 takes precedence)}
- H01G 4/1227: {based on alkaline earth titanates}
- H01G 4/1245: {containing also titanates}
- H01G 4/232: electrically connecting two or more layers of a stacked or rolled capacitor
- H01G 4/2325: {characterised by the material of the terminals}
- C04B 2235/66: Specific sintering techniques, e.g. centrifugal sintering
- C04B 2237/346: Titania or titanates
- C04B 2237/80: Joining the largest surface of one substrate with a smaller surface of the other substrate, e.g. butt joining or forming a T-joint
- H01G 4/252: the terminals being coated on the capacitive element (H01G4/232 takes precedence)
- H01G: CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE (selection of specified materials as dielectric H01B3/00; capacitors having potential barriers H10D1/62, H10K10/10)
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE

## Abstract

A multilayer ceramic electronic component includes a ceramic body including a laminate body including first and second surfaces opposing each other in a first direction, third and fourth surfaces opposing each other in a second direction, and fifth and sixth surfaces opposing each other in a third direction, and including a dielectric layer, and a first internal electrode and a second internal electrode stacked in the third direction with the dielectric layer interposed therebetween, a first and a second margin portion; a first connection portion and a second connection portion. The first connection portion includes a first lead electrode connected to the first internal electrode, and the second connection portion includes a second lead electrode connected to the second internal electrode.

## Claims

### Claim 1

A multilayer ceramic electronic component comprising:
a ceramic body including a laminate body including first and second surfaces opposing each other in a first direction, third and fourth surfaces opposing each other in a second direction, and fifth and sixth surfaces opposing each other in a third direction, and including a dielectric layer, and a first internal electrode and a second internal electrode stacked in the third direction with the dielectric layer interposed therebetween, a first margin portion disposed on the third surface of the laminate body, and a second margin portion disposed on the fourth surface of the laminate body;
a first connection portion disposed on the first surface of the laminate body; and
a second connection portion disposed on the second surface of the laminate body,
wherein the first connection portion includes a first lead electrode connected to the first internal electrode and a first ceramic layer disposed on the first lead electrode,
the second connection portion includes a second lead electrode connected to the second internal electrode and a second ceramic layer disposed on the second lead electrode,
the first lead electrode is led out to one surface of the first connection portion in the third direction, and the second lead electrode is led out to one surface of the second connection portion in the third direction,
among the first to sixth surfaces of the laminate body, the first lead electrode is disposed only on the first surface of the laminate body,
among the first to sixth surfaces of the laminate body, the second lead electrode is disposed only on the second surface of the laminate body,
the first ceramic layer covers at least a portion of the first lead electrode,
the second ceramic layer covers at least a portion of the second lead electrode,
a maximum value of a width of the first lead electrode and/or the second lead electrode in the second direction is smaller than a maximum value of a width of the ceramic body in the second direction, and
a maximum value of a height of the first lead electrode and/or the second lead electrode in the third direction is smaller than a maximum value of a height of the ceramic body in the third direction.

### Claim 2 (depends on 1)

The multilayer ceramic electronic component of claim 1, wherein the first internal electrode and the second internal electrode include one or more conductive metals selected from the group consisting of silver (Ag), palladium (Pd), gold (Au), platinum (Pt), nickel (Ni), copper (Cu), tin (Sn), tungsten (W), titanium (Ti), and alloys thereof.

### Claim 3 (depends on 1)

The multilayer ceramic electronic component of claim 1, wherein the first lead electrode and the second lead electrode include one or more conductive metals selected from the group consisting of silver (Ag), palladium (Pd), gold (Au), platinum (Pt), nickel (Ni), copper (Cu), tin (Sn), tungsten (W), titanium (Ti), and alloys thereof.

### Claim 4 (depends on 1)

The multilayer ceramic electronic component of claim 1, wherein the first internal electrode, the second internal electrode, the first lead electrode, and the second lead electrode include one or more conductive metals selected from the group consisting of silver (Ag), palladium (Pd), gold (Au), platinum (Pt), nickel (Ni), copper (Cu), tin (Sn), tungsten (W), titanium (Ti), and alloys thereof.

### Claim 5 (depends on 1)

The multilayer ceramic electronic component of claim 1, wherein the first ceramic layer and/or the second ceramic layer includes a component represented by (Ba1-xCax) (Ti1-y(Zr, Sn, Hf)y)O3 (0≤x≤1 and 0≤y≤0.5).

### Claim 6 (depends on 1)

The multilayer ceramic electronic component of claim 1, wherein the first connection portion includes a first auxiliary electrode disposed to be in contact with the first lead electrode,
the second connection portion includes a second auxiliary electrode disposed to be in contact with the second lead electrode,
the first auxiliary electrode is led out together with the first lead electrode, and
the second auxiliary electrode is led out together with the second lead electrode.

### Claim 7 (depends on 6)

The multilayer ceramic electronic component of claim 6, further comprising a first terminal electrode connected to the first lead electrode, and a second terminal electrode connected to the second lead electrode,
wherein the first terminal electrode and the second terminal electrode are disposed to be spaced apart from each other on a surface from which the first and second lead electrodes are led.

### Claim 8 (depends on 1)

The multilayer ceramic electronic component of claim 1, further comprising a first terminal electrode connected to the first lead electrode, and a second terminal electrode connected to the second lead electrode,
wherein the first terminal electrode and the second terminal electrode are disposed to be spaced apart from each other on a surface of the capacitor body from which the first and second lead electrodes are led.

### Claim 9 (depends on 1)

The multilayer ceramic electronic component of claim 1, further comprising a first terminal electrode connected to the first lead electrode, and a second terminal electrode connected to the second lead electrode,
wherein the first terminal electrode and the second terminal electrode are disposed to be spaced apart from each other on a surface from which the first and second lead electrodes are led.

### Claim 10 (depends on 9)

The multilayer ceramic electronic component of claim 9, further comprising:
a first plating layer disposed on the first lead electrode; and
a second plating layer disposed on the second lead electrode.

### Claim 11 (depends on 1)

The multilayer ceramic electronic component of claim 1, further comprising:
a first plating layer disposed on the first lead electrode; and
a second plating layer disposed on the second lead electrode.

### Claim 12 (depends on 1)

The multilayer ceramic electronic component of claim 1, further comprising:
a first connection electrode disposed to cover the first lead electrode and the first ceramic layer; and
a second connection electrode disposed to cover the second lead electrode and the second ceramic layer,
wherein at least portions of the first lead electrode and the second lead electrode are exposed in the first direction.

### Claim 13 (depends on 1)

The multilayer ceramic electronic component of claim 1, wherein the first lead electrode and the second lead electrode are led out to opposite surfaces of the ceramic body in the third direction.

### Claim 14 (depends on 1)

The multilayer ceramic electronic component of claim 1, wherein a length in the first direction is greater than a width in the second direction.

### Claim 15 (depends on 1)

The multilayer ceramic electronic component of claim 1, wherein a length in the first direction is smaller than a width in the second direction.

### Claim 16

A multilayer ceramic electronic component comprising:
a ceramic body including a laminate body including first and second surfaces opposing each other in a first direction, third and fourth surfaces opposing each other in a second direction, and fifth and sixth surfaces opposing each other in a third direction, and including a dielectric layer, and a first internal electrode and a second internal electrode stacked in the second direction with the dielectric layer interposed therebetween, a first margin portion disposed on the third surface of the laminate body, and a second margin portion disposed on the fourth surface of the laminate body;
a first connection portion disposed on the first surface of the laminate body; and
a second connection portion disposed on the second surface of the laminate body,
wherein the first connection portion includes a first lead electrode connected to the first internal electrode and a first ceramic layer disposed on the first lead electrode,
the second connection portion includes a second lead electrode connected to the second internal electrode and a second ceramic layer disposed on the second lead electrode,
the first lead electrode is led out to one surface of the first connection portion in the third direction,
the second lead electrode is led out to one surface of the second connection portion in the third direction,
among the first to sixth surfaces of the laminate body, the first lead electrode is disposed only on the first surface of the laminate body, and
among the first to sixth surfaces of the laminate body, the second lead electrode is disposed only on the second surface of the laminate body.

### Claim 17 (depends on 16)

The multilayer ceramic electronic component of claim 16, wherein a maximum value of a width of the first lead electrode and/or the second lead electrode in the second direction is smaller than a maximum value of a width of the ceramic body in the second direction.

### Claim 18 (depends on 16)

The multilayer ceramic electronic component of claim 16, wherein a maximum value of a height of the first lead electrode and/or the second lead electrode in the third direction is a maximum value or less of a height of the ceramic body in the third direction.

### Claim 19 (depends on 16)

The multilayer ceramic electronic component of claim 16, wherein a length in the first direction is greater than a width in the second direction.

### Claim 20 (depends on 16)

The multilayer ceramic electronic component of claim 16, wherein a length in the first direction is smaller than a width in the second direction.

### Claim 21

A multilayer ceramic electronic component comprising:
a ceramic body including a laminate body including first and second surfaces opposing each other in a first direction, third and fourth surfaces opposing each other in a second direction, and fifth and sixth surfaces opposing each other in a third direction and having a first internal electrode and a second internal electrode stacked in the third direction with a dielectric layer interposed therebetween, the first internal electrode extending from the first surface of the laminate body and the second internal electrode extending from the second surface of the laminate body;
a first connection portion including a first lead electrode connected to the first internal electrode, and a first ceramic layer covering the first lead electrode and being in contact with the ceramic body; and
a second connection portion including a second lead electrode connected to the second internal electrode, and a second ceramic layer covering the second lead electrode and being in contact with the ceramic body,
wherein the first lead electrode includes one end led out to one surface of the first connection portion, and the second lead electrode includes one end led out to one surface of the second connection portion,
the first ceramic layer is in contact with the first surface of the laminate body,
the second ceramic layer is in contact with the second surface of the laminate body,
a maximum value of a width of the first lead electrode and/or the second lead electrode in the second direction is smaller than a maximum value of a width of the ceramic body in the second direction, and
a maximum value of a height of the first lead electrode and/or the second lead electrode in the third direction is smaller than a maximum value of a height of the ceramic body in the third direction.

### Claim 22 (depends on 21)

The multilayer ceramic electronic component of claim 21, wherein the capacitor body further includes first and second margin portions respectively disposed on the third and fourth surfaces of the laminate body, and
the first and second margin portions include a ceramic material.

### Claim 23 (depends on 22)

The multilayer ceramic electronic component of claim 22, wherein the first and second margin portions are in contact with the first and second ceramic layers.

### Claim 24 (depends on 21)

The multilayer ceramic electronic component of claim 21, further comprising a first terminal electrode connected to the one end of the first lead electrode and a second terminal electrode connected to the one end of the second lead electrode.

### Claim 25 (depends on 21)

The multilayer ceramic electronic component of claim 21, wherein the first lead electrode includes another end led out to another surface of the first connection portion, and the second lead electrode includes another end led out to another surface of the second connection portion.

### Claim 26 (depends on 21)

The multilayer ceramic electronic component of claim 21, wherein among the one end of the first lead electrode and another end of the first lead electrode opposing the one end of the first lead electrode, the one end of the first lead electrode is the only end led out to the first connection portion, and
among the one end of the second lead electrode and another end of the second lead electrode opposing the one end of the second lead electrode, the one end of the second lead electrode is the only end led out to the second connection portion.

### Claim 27 (depends on 21)

The multilayer ceramic electronic component of claim 21, wherein the first lead electrode covers only a portion of the first surface of the laminate body, and the second lead electrode covers only a portion of the second surface of the laminate body.

### Claim 28

A method of manufacturing a multilayer ceramic electronic component, the method comprising:
forming a body including a laminate body having a first internal conductive paste layer and a second internal conductive paste layer with an internal ceramic paste layer interposed therebetween;
forming a first conductive paste layer on one surface of the body, and a first ceramic paste layer covering the first conductive paste layer and being in contact with the body;
forming a second conductive paste layer on another surface of the body, and a second ceramic paste layer covering the second conductive paste layer and being in contact with the body; and
simultaneously sintering the body, the first conductive paste layer, the first ceramic paste layer, the second conductive paste layer, and the second ceramic paste layer,
wherein a first lead electrode, formed of the first conductive paste layer by the sintering, is connected to a first internal electrode, formed of the first conductive paste layer by the sintering,
a second lead electrode, formed of the second conductive paste layer by the sintering, is connected to a second internal electrode, formed of the second conductive paste layer by the sintering,
the first lead electrode includes an end exposed from a first ceramic layer, formed of the first ceramic paste layer by the sintering, and the second lead electrode includes an end exposed from a second ceramic layer, formed of the second ceramic paste layer by the sintering,
the laminate body, after the sintering, includes first and second surfaces opposing each other in a first direction, third and fourth surfaces opposing each other in a second direction, and fifth and sixth surfaces opposing each other in a third direction,
a ceramic body, formed of the body by the sintering, includes the first internal electrode and the second internal electrode stacked in the third direction with a dielectric layer formed of the internal ceramic paste and interposed therebetween, a first margin portion disposed on the third surface, and a second margin portion disposed on the fourth surface,
among the first to sixth surfaces of the laminate body, the first lead electrode is disposed only on the first surface of the laminate body,
among the first to sixth surfaces of the laminate body, the second lead electrode is disposed only on the second surface of the laminate body,
the first ceramic layer covers at least a portion of the first lead electrode,
the second ceramic layer covers at least a portion of the second lead electrode,
a maximum value of a width of the first lead electrode and/or the second lead electrode in the second direction is smaller than a maximum value of a width of the ceramic body in the second direction, and
a maximum value of a height of the first lead electrode and/or the second lead electrode in the third direction is smaller than a maximum value of a height of the ceramic body in the third direction.

### Claim 29 (depends on 28)

The method of claim 28, wherein forming the body further includes:
prior to the forming the first conductive paste layer, the first ceramic paste layer, the second conductive paste layer, and the second ceramic paste layer, forming first and margin paste portions on opposing surfaces of the laminate body, respectively, and
the first and margin paste portions are simultaneously sintered with the body, the first conductive paste layer, the first ceramic paste layer, the second conductive paste layer, and the second ceramic paste layer, such that the first and margin paste portions are formed as the first and second margin portions, respectively, by the sintering.

### Claim 30 (depends on 28)

The method of claim 28, further comprising forming a first terminal electrode connected to the end of the first lead electrode and a second terminal electrode connected to the end of the second lead electrode.
