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US 11,905,227 B2Granted
Oligomerization of olefins
AssigneeExxonMobil Chemical Patents Inc.
InventorsShiwen Li, Alan A. Galuska, Teng Xu
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Abstract
A process for olefin oligomerization can include contacting a feedstock comprising Cn and C2n olefins/paraffins under oligomerization conditions in the presence of an oligomerization catalyst, wherein n is 2 to 15; and recovering an oligomeric product comprising C3n oligomers having a branching index of less than 2.1. Optionally, the feedstock can further comprise C3n olefins/paraffins.
Claims10
A process for olefin oligomerization, the process comprising:
- contacting a feedstock comprising Cn and C2n olefins/paraffins under oligomerization conditions in a reactor in the presence of an oligomerization catalyst wherein the catalyst comprises a ZSM-23 catalyst having no amine treatment, wherein n is 4 and the feedstock comprises 45 wt % to 75 wt % C4 and 15 wt % to 50 wt % C8;
- forming an oligomeric product comprising C12 oligomers, wherein the C12 oligomers have a branching index of less than 2.1;
- and
- recycling at least a first portion of the oligomeric product to the reactor.
1 more element
Dependencies are inferred from the claim text.