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US 11,905,177 B2Granted
Storage medium and method for separating, storing and transporting chlorine from chlorine-containing gases
AssigneeCovestro Intellectual Property GmbH & Co. KG
InventorsMaxime Paven, Yuliya Schiesser, Rainer Weber, Gerhard Langstein, Vinh Trieu, Sebastian Hasenstab-Riedel, Nico Schwarze, Simon Steinhauer
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Abstract
The invention relates to a storage medium and to a method for using a storage medium based on ionic compounds, which can reversibly absorb and store chlorine and chlorine from process gases, and which can release the same again by changing the ambient conditions, wherein the storage medium can be reused for this task after discharge.
Claims13
A process for the reversible storage of chlorine from chlorine-containing gas in a storage medium, the process comprising:
- contacting chlorine-containing gas with a liquid storage medium in a first step to form a loaded storage medium, the liquid storage medium comprising an ionic compound (I) having the formula
- N—R1mR2nR3o+Clr− (I);
- wherein the loaded storage medium comprises chlorine from the chlorine- containing gas in an ionic compound (III) having the formula
- N—R1mR2nR3o+Cl(r+2)− (III);
- wherein each of R1, R2 and R3 independently comprise an alkyl radical selected from the following group:
- methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, and 2-methylpropyl;
- wherein R1, R2, and R3 collectively comprise more than one type of alkyl radical:
- wherein m is an integer in a range of 0 to 3, n is an integer in a range of 0 to 3, o is an integer in a range of 0 to 3, and wherein a sum consisting of m, n, and o is 4;
- and
- wherein r is an odd number in a range of 1 to 7, and wherein s is an odd number in a range of 1 to 7;
- removing chlorine from the loaded storage medium by increasing a temperature of the storage medium and/or lowering a partial pressure above the storage medium, thereby discharging chlorine.
8 more elements
Dependencies are inferred from the claim text.