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US 11,901,558 B2Granted
Lithium niobate and method for producing the same
AssigneeToyota Jidosha Kabushiki Kaisha
InventorsKoichi Sugiura, Nariaki Miki, Kazuki Muraishi, Kengo Matsuo
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Abstract
A lithium niobate with high lithium ion conductivity. Disclosed is a method for producing a lithium niobate for use in a covering layer covering at least part of a surface of cathode active material particles, the method comprising: preparing a solution containing niobium ions and lithium ions, drying the solution to obtain a lithium niobate precursor, and heating the lithium niobate precursor at a temperature of from 250° C. to 300° C. for a heating time of more than 0 minute and 10 minutes or less.
Claims1
A method for producing an all-solid-state battery,
- the method comprising:
- preparing a solution containing niobium ions and lithium ions,
- drying the solution to obtain a lithium niobate precursor, and
- obtaining a lithium niobate by heating the lithium niobate precursor at a temperature of from 250° C. to 300° C. for a heating time of more than 0 minute and 10 minutes or less, and
- wherein an A/B ratio value of the lithium niobate between a first peak intensity value A at a diffraction angle (2θ) of 23.7°±0.5° and a second peak intensity value B at a diffraction angle (2θ) of 53.2°±0.5°, is 1.96 or more and 2.54 or less, and the peak intensities are observed by X-ray diffraction (XRD) measurement using CuKα radiation;
- wherein the all-solid-state battery comprises a cathode comprising a cathode layer, an anode comprising an anode layer, and a solid electrolyte layer disposed between the cathode layer and the anode layer;
- wherein the cathode layer contains composite active material particles;
- wherein the composite active material particles are composed of cathode active material particles and a covering layer;
- wherein the covering layer contains the lithium niobate and covering at least part of the surface of the cathode active material particles;
- wherein the solid electrolyte layer contains a sulfide-based solid electrolyte;
- and
- wherein the sulfide-based solid electrolyte contains 10LiI-15LiBr-37.5Li3PS4 as a raw material composition.
9 more elements
Dependencies are inferred from the claim text.