# US 11,898,232 B2 · High-strength alloy based on aluminium and method for producing articles therefrom

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- Number: US 11,898,232 B2
- Document ID: US11898232B2
- Status: Granted
- Kind: B2
- Application number: 15/764,186
- Filed: 2016-04-29
- Published: 2018-09-27
- Granted: 2024-02-13
- Earliest claimed: 2015-09-29
- Assignees: United Company RUSAL Engineering and Technology Centre LLC
- Applicants: United Company RUSAL Engineering and Technology Centre LLC
- Inventors: Viktor Khrist'yanovich Mann; Aleksandr Nikolaevich Alabin; Anton Valer'evich Frolov; Aleksandr Olegovich Gusev; Aleksandr Yur'evich Krokhin; Nikolaj Aleksandrovich Belov
- Web page: https://patentgrep.com/patent/US11898232B2

## CPC

- C22F 1/053: of alloys with zinc as the next major constituent
- C22C 21/10: with zinc as the next major constituent
- C22F: CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS (surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by this subclass, C23F17/00)
- C22C: ALLOYS (treatment of alloys C21D, C22F)

## Abstract

The present invention relates to metallurgy of high-strength cast and wrought alloys based on aluminum, and can be used in missioncritical designs operable under load, in the transport field, sports industry, casings for electronic devices, and other industrial sectors. The technical result aims to enhance mechanical characteristics of articles produced from the alloy by precipitation hardening caused by secondary phases in the age-hardening process while providing high workability during casting. The claimed high-strength alloy comprises zinc, magnesium, nickel, iron, copper, zirconium, and at least one metal selected from a group consisting of titanium, scandium and chromium, with the following amounts in, wt %: zinc 3.8-7.4; magnesium 1.2-2.6; nickel 0.5-2.5; iron 0.3-1.0; copper 0.001-0.25; zirconium 0.05-0.2; titanium 0.01-0.05; scandium 0.05-0.10; chromium 0.04-0.15; and the remainder being aluminum, wherein iron and nickel form aluminides of the Al9FeNi phase, which originates from eutectic transformation and represents at least 2 vol %.

## Claims

### Claim 1

A high-strength aluminum-based alloy consisting of aluminum, zinc, magnesium, nickel, iron, copper, zirconium, and one or more metal or metals selected from a group consisting of titanium, scandium, and chromium with the following ratios, expressed in terms of wt. %:
Zinc
3.8-4.5
Magnesium
1.2-1.5
Nickel
0.5-0.7
Iron
0.3-0.45
Copper
0.01-0.25
Zirconium
0.11-0.2
Titanium
up to 0.02
Scandium
up to 0.10
Chromium
up to 0.10
Aluminum
the rest,
wherein iron and nickel create aluminides of an Al9FeNi eutectic phase wherein the volume fraction is in the range 2.0-2.4 vol. %, wherein iron and nickel create eutectic aluminides having a particle size no more than 2 μm, wherein the Ni/Fe ratio of the alloy is ≥1, wherein zirconium and titanium are substantially in the form of secondary phases having a particle size of no more than 20 nm and having a L12 crystal lattice.

### Claim 2 (depends on 1)

The alloy of claim 1, wherein aluminum is produced by electrolysis using an inert anode.

### Claim 3 (depends on 1)

A method for producing a wrought article made of a high-strength alloy, the method comprising:
preparing a melt,
producing ingots by melt crystallization,
homogenizing annealing of the ingots to produce homogenized ingots,
producing wrought articles by working the homogenized ingots,
heating the wrought articles,
holding the wrought articles for hardening at a predetermined temperature and water hardening of the wrought articles,
aging the wrought articles,
wherein the alloy is in accordance with claim 1, wherein the ingots are homogenized by annealing at a temperature of no more than 560° C.,
wherein the wrought article is held for hardening at a temperature in the range of 380-450° C., and wherein the wrought article is aged a temperature of no more than 170° C.

### Claim 4 (depends on 3)

The method in accordance with claim 3, wherein the wrought article is aged at least in two steps: at a first step at a temperature of 90-130° C., and at a second step at a temperature up to 170° C.

### Claim 5 (depends on 3)

The method in accordance with claim 3, wherein the wrought article is aged with holding at a room temperature for at least 72 hours.

### Claim 6 (depends on 1)

A method for producing castings from a high-strength alloy, the method comprising:
preparing a melt,
producing a casting,
heating the casting,
holding the casting for hardening at a predetermined temperature,
water hardening the casting and aging the casting,
wherein the alloy is in accordance with claim 1,
wherein the casting is held for hardening at a temperature of 380-560° C., and the casting is aged at a temperature of no more than 170° C.

### Claim 7 (depends on 3)

The method in accordance with claim 3, wherein the casting is aged at least in two steps: at a first step at a temperature of 90-130° C., and at a second step at a temperature up to 170° C.

### Claim 8 (depends on 3)

The method in accordance with claim 3, wherein the casting is aged with holding at a room temperature for at least 72 hours.