# US 11,898,121 B2 · Dishwashing composition having improved sudsing > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 11,898,121 B2 - Document ID: US11898121B2 - Status: Granted - Kind: B2 - Application number: 17/505,675 - Filed: 2021-10-20 - Published: 2022-04-28 - Granted: 2024-02-13 - Earliest claimed: 2020-10-23 - Assignees: The Procter & Gamble Company - Applicants: The Procter & Gamble Company - Inventors: Jana Verena Margarethe Herzberger; Pieter Jan Maria Saveyn; Steven Daryl Smith; Evelyne Johanna Lutgarde Van Hecke; Valerie Wong - Web page: https://patentgrep.com/patent/US11898121B2 ## CPC - C11D 1/94: Mixtures with anionic, cationic or non-ionic compounds - C11D 1/14: derived from aliphatic hydrocarbons or mono-alcohols - C11D 1/22: derived from aromatic compounds - C11D 1/75: Amino oxides - C11D 3/37: Polymers {(polymeric surface-active agents C11D1/008; polysaccharides C11D3/222)} - C11D 3/3753: {Polyvinylalcohol; Ethers or esters thereof} - C11D 1/29: Sulfates of polyoxyalkylene ethers - C11D 1/72: Ethers of polyoxyalkylene glycols - C11D 1/88: Ampholytes; Electroneutral compounds {(C11D1/002, C11D1/004, C11D1/008 take precedence)} - C11D 2111/14: Hard surfaces - C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL ## Abstract The need for a liquid hand-dishwashing composition which provides further improved sudsing volume and longevity when washing dishware using diluted liquid hand dishwashing compositions, especially in the presence of greasy soil, while still providing the desired cleaning, is met when the composition is formulated with from 5% to 50% of a sudsing surfactant system and from 0.05% to 5.0% polyvinyl acetal polymer. ## Claims ### Claim 1 A liquid hand dishwashing cleaning composition comprising: a. from about 5% to about 50% by weight of the composition of a surfactant system; b. from about 0.05% to about 5.0% by weight of the composition of a polyvinyl acetal polymer wherein the polyvinyl acetal polymer consists of polyvinyl alcohol and polyvinyl acetal subunits and optionally polyvinyl acetate subunits, and further wherein the polyvinyl acetal polymer has an average degree of acetalization of from about 0.5 mol % to about 10 mol %, and the polyvinyl acetal subunit has a structure according to structure (I), wherein R represents C1 to C11 alkyl: ### Claim 2 (depends on 1) The liquid hand dishwashing cleaning composition according to claim 1, wherein the polyvinyl acetal polymer is present at a level of from about 0.1% to about 3.5% by weight of the composition. ### Claim 3 (depends on 2) The liquid hand dishwashing cleaning composition according to claim 2, wherein the polyvinyl acetal polymer is present at a level of from about 0.1% to about 2.0% by weight of the composition. ### Claim 4 (depends on 1) The liquid hand dishwashing cleaning composition according to claim 1, wherein the polyvinyl acetal polymer has polyvinyl acetate subunits. ### Claim 5 (depends on 1) The liquid hand dishwashing cleaning composition according to claim 1, wherein R represents a C3 to C9 alkyl. ### Claim 6 (depends on 1) The liquid hand dishwashing cleaning composition according to claim 1, wherein the polyvinyl acetal polymer has an average viscosity of from about 1 mPa·s to about 25 mPa·s when measured as an about 4% aqueous solution at about 20° C. in demineralised water, wherein the viscosity of the polyvinyl alcohol aqueous solution is measured using a Brookfield LV type viscometer with UL adapter as described in British Standard EN ISO 15023-2:2006 Annex E Brookfield Test method. ### Claim 7 (depends on 1) The liquid hand dishwashing cleaning composition according to claim 1, wherein the polyvinyl acetal polymer has an average degree of hydrolysis of from about 45% to about 98%. ### Claim 8 (depends on 7) The liquid hand dishwashing cleaning composition according to claim 7, wherein the polyvinyl acetal polymer has an average degree of hydrolysis of from about 75% to about 90%. ### Claim 9 (depends on 1) The liquid hand dishwashing cleaning composition according to claim 1, wherein the liquid hand dishwashing cleaning composition comprises from about 8% to about 45% by weight of the total composition of the surfactant system. ### Claim 10 (depends on 1) The liquid hand dishwashing cleaning composition according to claim 1, wherein the surfactant system comprises anionic surfactant. ### Claim 11 (depends on 10) The liquid hand dishwashing cleaning composition according to claim 10, wherein the anionic surfactant is an alkyl sulphated anionic surfactant selected from the group consisting of: alkyl sulphate, alkyl alkoxy sulphate, and mixtures thereof. ### Claim 12 (depends on 11) The composition according to claim 11, wherein the surfactant system comprises alkyl sulphated anionic surfactant, and wherein the alkyl sulphated anionic surfactant has an average alkyl chain length of from 8 to 18 carbon atoms. ### Claim 13 (depends on 11) The composition according to claim 11, wherein the alkyl sulphated anionic surfactant has an average degree of alkoxylation, of less than about 5. ### Claim 14 (depends on 11) The composition according to claim 11, wherein the alkyl sulphated anionic surfactant has a weight average degree of branching of more than about 10%. ### Claim 15 (depends on 10) The liquid hand dishwashing cleaning composition according to claim 10, wherein the surfactant system further comprises a co-surfactant selected from the group consisting of an amphoteric surfactant, a zwitterionic surfactant and mixtures thereof. ### Claim 16 (depends on 12) The liquid hand dishwashing cleaning composition according to claim 12, wherein the surfactant system further comprises an amphoteric surfactant selected from amine oxide surfactants. ### Claim 17 (depends on 15) The liquid hand dishwashing cleaning composition according to claim 15, wherein the weight ratio of the anionic surfactant to the co-surfactant is from about 1:1 to about 8:1.