# US 11,898,090 B2 · Diverting agent and method of filling fracture in well using the same

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- Number: US 11,898,090 B2
- Document ID: US11898090B2
- Status: Granted
- Kind: B2
- Application number: 17/563,637
- Filed: 2021-12-28
- Published: 2022-04-21
- Granted: 2024-02-13
- Earliest claimed: 2019-07-03
- Assignees: Mitsubishi Chemical Corporation
- Applicants: Mitsubishi Chemical Corporation
- Inventors: Chizuko Furo; Yuya Kanamori; Yasuhiro Hirano
- Web page: https://patentgrep.com/patent/US11898090B2

## CPC

- C09K 8/508: macromolecular compounds {(C09K8/512 takes precedence)}
- C09K 8/5083: {obtained by reactions only involving carbon-to-carbon unsaturated bonds}
- C09K 8/68: containing organic compounds
- C09K 8/80: Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
- C09K 8/88: macromolecular compounds
- E21B 43/26: by forming crevices or fractures
- E21B 43/267: reinforcing fractures by propping
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS

## Abstract

A diverting agent which has performance to release filling due to biodegradability, can be quickly removed after a certain period of time, and has an excellent filling property with respect to a fracture in a well is provided. The diverting agent contains particles having a particle diameter of 1,700 μm or more in an amount of 10 to 70 mass %, particles having a particle diameter of 500 μm or more and less than 1,700 μm in an amount of 20 to 80 mass %, and particles having a particle diameter of less than 250 μm in an amount of 5 to 40 mass %, and the diverting agent contains a biodegradable resin in an amount of 10 mass % or more.

## Claims

### Claim 1

A diverting agent comprising:
particles having an average particle diameter of 1,700 μm or more in an amount of 10 to 70 mass % relating to the total mass of the diverting agent;
particles having an average particle diameter of 500 μm or more and less than 1,700 μm in an amount of 20 to 80 mass % relating to the total mass of the diverting agent; and
particles having an average particle of less than 250 μm in an amount of 5 to 40 mass % relating to the total mass of the diverting agent,
wherein 10 mass % or more of the diverting agent relating to the total mass of the diverting agent is a biodegradable resin.

### Claim 2 (depends on 1)

The diverting agent according to claim 1,
wherein when 24 g of the diverting agent is added to 400 mL of a 0.60 mass % aqueous solution of guar gum and dispersed at 23° C. for 60 minutes to obtain a dispersion liquid having a diverting agent concentration of 6 mass %, the dispersion liquid is subjected to pressure dehydration at pressure of 0.4 MPa using a pressure dehydration device including a drainage portion having a slit having a width of 2 mm, an cumulative dehydration amount y with respect to a square root x of a time is obtained, and a regression line represented by the following formula (A) is calculated by a least-squares method from a scatter diagram plotted on a graph in which the square root x of the time is plotted on a horizontal axis and the cumulative dehydration amount y is plotted on a vertical axis, a water permeability coefficient represented by the slope a of the following formula (A) is in a range of 0.0 to 4.0,
y=ax+b (A)
in the formula (A), y is a cumulative dehydration amount (gram), x is the square root of the time (minutes) elapsed from start of pressurization, a and b are the slope and an intercept of the regression line, and 0<x≤2.

### Claim 3 (depends on 1)

The diverting agent according to claim 1,
wherein the biodegradable resin contains a polyvinyl alcohol-based resin.

### Claim 4 (depends on 3)

The diverting agent according to claim 3,
wherein the polyvinyl alcohol-based resin has a degree of saponification of 90 mol % or more.

### Claim 5 (depends on 3)

The diverting agent according to claim 3,
wherein the polyvinyl alcohol-based resin is a polyvinyl alcohol-based resin having a primary hydroxyl group in a side chain.

### Claim 6 (depends on 1)

A method of temporarily filling a fracture generated in a well, the method comprising:
allowing the diverting agent according to claim 1 to flow into a fracture to be filled with a flow of a fluid in the well.
