Method for producing silica sol having elongated particle shape
AssigneeNissan Chemical Corporation
InventorsSatoru Murakami, Takuya Fukuoka, Kazuya Kuroiwa
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AssigneeNissan Chemical Corporation
InventorsSatoru Murakami, Takuya Fukuoka, Kazuya Kuroiwa
Estimating the term…
A method for producing a silica sol containing a small amount of metal impurities and in which colloidal silica having an elongated particle shape dispersed in a solvent, includes: preparing a raw material liquid by adding a compound as an anion source selected from inorganic acids, organic acids, and their ammonium salts, and ammonia to a colloidal aqueous solution of activated silica having an SiO2 concentration of 1 to 6% by mass and a pH of 2 to 5 so that the mass ratio of the compound to SiO2 is 3.0 to 7.0%; and heating the raw material liquid at 80 to 200° C. for 0.5 to 20 hours. The elongated colloidal silica particles exhibit a DL/DB ratio of 2.5 or more. DL is an average particle diameter as measured by the dynamic light scattering method. DB is a primary particle diameter as measured by the nitrogen gas adsorption method.
A method for producing a silica sol containing elongated colloidal silica particles dispersed in a liquid medium and having an SiO2 concentration of 6 to 30% by mass, wherein the elongated colloidal silica particles have a particle length of 50 to 1,000 nm as determined by observation with an electron microscope and exhibit a DL/DB ratio of 2.5 or more and a DL of 30 to 300 nm wherein DL is an average particle diameter (nm) as measured by the dynamic light scattering method, and DB is a primary particle diameter (nm) as measured by the nitrogen gas adsorption method, the production method comprising the following steps (a) and (b):
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