# US 11,897,769 B2 · Process for H2 and syngas production

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- Number: US 11,897,769 B2
- Document ID: US11897769B2
- Status: Granted
- Kind: B2
- Application number: 17/407,422
- Filed: 2021-08-20
- Published: 2023-02-23
- Granted: 2024-02-13
- Earliest claimed: 2021-08-20
- Assignees: Air Products and Chemicals, Inc.
- Applicants: Air Products and Chemicals, Inc.
- Inventors: Xiang-Dong Peng; Yu Zhang; Tori Dawn Courtney
- Web page: https://patentgrep.com/patent/US11897769B2

## CPC

- C01B 3/382: Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
- C01B 3/48: followed by reaction of water vapour with carbon monoxide
- C01B 3/52: by contacting with liquids; Regeneration of used liquids
- C01B 2203/0205: containing a reforming step
- C01B 2203/0233: the reforming step being a steam reforming step
- C01B 2203/0244: the reforming step being an autothermal reforming step, e.g. secondary reforming processes
- C01B 2203/025: containing a partial oxidation step
- C01B 2203/0255: containing a non-catalytic partial oxidation step
- C01B 2203/0283: containing a CO-shift step, i.e. a water gas shift step
- C01B 2203/0415: Purification by absorption in liquids
- C01B 2203/0475: the impurity being carbon dioxide
- C01B 2203/0811: by combustion of fuel
- C01B 2203/0833: Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
- C01B 2203/0883: by indirect heat exchange
- C01B 2203/0894: Generation of steam
- C01B 2203/1241: Natural gas or methane
- C01B 2203/127: Catalytic desulfurisation
- C01B 2203/1276: Mixing of different feed components
- C01B 2203/142: At least two reforming, decomposition or partial oxidation steps in series
- C01B 2203/146: At least two purification steps in series
- C01B 2203/148: involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
- Y02P 20/129: Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

A process for producing syngas that uses the syngas product from an oxygen-fired reformer to provide all necessary heating duties, which eliminates the need for a fired heater. Without the flue gas stream leaving a fired heater, all of the carbon dioxide produced by the reforming process is concentrated in the high-pressure syngas stream, allowing essentially complete carbon dioxide capture.

## Claims

### Claim 1

A process for producing syngas, the process comprising:
reacting a reformer feed stream comprising methane and an oxidant selected from the group consisting of water and carbon dioxide with an oxygen-enriched stream to produce a first syngas stream comprising hydrogen, carbon monoxide, and carbon dioxide;
heating a preheated mixed feed stream by indirect heat exchange with the first syngas stream to produce the reformer feed stream and a second syngas stream;
heating a boiler feed water stream by indirect heat exchange with the second syngas stream to produce a saturated steam and a third syngas stream; and
heating the saturated steam by indirect heat exchange with the third syngas stream to produce a superheated steam and a fourth syngas stream.

### Claim 2 (depends on 1)

The process of claim 1, wherein methane and oxidant in the preheated mixed feed stream are reacted to form hydrogen, carbon monoxide, and carbon dioxide while being heated by indirect heat exchange with the first syngas stream.

### Claim 3 (depends on 1)

The process of claim 1, further comprising injecting a process steam into the first syngas stream before transferring heat by indirect heat exchange with the preheated mixed feed stream.

### Claim 4 (depends on 1)

The process of claim 1, wherein the second syngas stream has a temperature that is greater than 815° C.

### Claim 5 (depends on 1)

The process of claim 1, wherein the preheated mixed feed stream has a temperature that is less than 455° C.

### Claim 6 (depends on 1)

The process of claim 1, wherein the saturated steam is heated only by the third syngas stream.

### Claim 7 (depends on 1)

The process of claim 1, further comprising reacting CO with H2 in the third syngas stream or a stream derived from the third syngas stream to produce a methanated H2 product stream comprising H2 and CH4.

### Claim 8 (depends on 1)

The process of claim 1, further comprising heating a mixed feed stream by indirect heat exchange with the fourth syngas stream to produce the preheated mixed feed stream and a fifth syngas stream.

### Claim 9 (depends on 8)

The process of claim 8, wherein the mixed feed stream is heated only by the fourth syngas stream.

### Claim 10 (depends on 8)

The process of claim 8, further comprising combining a CO2-rich stream with the mixed feed stream.

### Claim 11 (depends on 8)

The process of claim 8, further comprising separating the third syngas stream or a stream derived from the third syngas stream to produce a coldbox tail gas stream and any of a purified CO product, a purified H2 product, and a syngas product; and
combining at least 98% of the coldbox tail gas stream with any of the following: the mixed feed stream, the preheated mixed feed stream, the reformer feed stream, the first syngas stream, and a stream derived from the first syngas stream.

### Claim 12 (depends on 8)

The process of claim 8, further comprising reacting at least a portion of the water with carbon monoxide in the fourth syngas stream to produce hydrogen and carbon dioxide.

### Claim 13 (depends on 12)

The process of claim 12, wherein a shift steam stream is combined with the fourth syngas stream prior to reacting the at least a portion of the water with carbon monoxide.

### Claim 14 (depends on 8)

The process of claim 8, further comprising the following steps:
heating a hydrocarbon feedstock stream by indirect heat exchange with the fifth syngas stream or a stream derived from the fifth syngas stream to produce a preheated hydrocarbon feedstock stream;
combining the preheated hydrocarbon feedstock stream with a steam feed stream to produce the mixed feed stream; and
heating a water stream by indirect heat exchange with the fifth syngas stream or a stream derived from the fifth syngas stream to produce the boiler feed water stream.

### Claim 15 (depends on 14)

The process of claim 14, further comprising separating one of the fifth syngas stream or a stream derived from the fifth syngas stream into a carbon dioxide-enriched stream and a carbon dioxide-depleted stream;
wherein a molar flow rate of carbon dioxide in the carbon dioxide-enriched stream is greater than 95% of a molar flow rate of carbon dioxide in the fifth syngas stream or the stream derived from the fifth syngas stream.

### Claim 16 (depends on 1)

The process of claim 1, further comprising the steps of:
separating the fourth syngas stream or a stream derived from the fourth syngas stream into a hydrogen-enriched stream and a hydrogen-depleted stream; and
combining at least 98% of the hydrogen-depleted stream with any of the following: the mixed feed stream, the preheated mixed feed stream, the reformer feed stream, the first syngas stream, and a stream derived from the first syngas stream.

### Claim 17 (depends on 16)

The process of claim 16, further comprising combining a CO2-rich stream with the hydrogen-depleted stream.

### Claim 18 (depends on 16)

The process of claim 16, further comprising dividing a portion of the superheated steam to produce an export steam; wherein a ratio of the mass flow rate of the export steam to the mass flow rate of the hydrogen-enriched stream is less than 60.