# US 11,896,709 B2 · Natural vegetable source based hair colour > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 11,896,709 B2 - Document ID: US11896709B2 - Status: Granted - Kind: B2 - Application number: 18/173,971 - Filed: 2023-02-24 - Published: 2023-08-31 - Granted: 2024-02-13 - Earliest claimed: 2023-02-24 - Assignees: Godrej Consumer Products Limited - Applicants: Godrej Consumer Products Ltd. - Inventors: Venkateswara Yadlapalli; Adrija Jha; John Naik; Manoj Gaur; Reena Bibals; Rajan Raghavachari; Rupinder Rawat - Web page: https://patentgrep.com/patent/US11896709B2 ## CPC - A61K 8/9789: Magnoliopsida [dicotyledons] - A61K 8/19: containing inorganic ingredients - A61K 8/20: Halogens; Compounds thereof - A61Q 5/065: {Preparations for temporary colouring the hair, e.g. direct dyes} - A61Q 5/10: Preparations for permanently dyeing the hair - A61K 2800/42: Colour properties - A61K 2800/48: Thickener, Thickening system - A61K: PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES (devices or methods specially adapted for bringing pharmaceutical products into particular physical or administering forms A61J3/00; chemical aspects of, or use of materials for deodorisation of air, for disinfection or sterilisation, or for bandages, dressings, absorbent pads or surgical articles A61L; soap compositions C11D) - A61Q: SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS ## Abstract The present invention describes a novel natural hair colour composition containing (a) a mixture of basic salt which aid in opening the hair cuticle and facilitating better penetration of dye which is natural plant-based extract; (b) a metal salt based mordanting agent which form a dye-metal complex. The invention further describes 2 step method of application which give better penetration and hence improved colour delivery and wash off resistance. ## Claims ### Claim 1 A two-part natural colour composition for dyeing keratinous fibres, including natural human hair, wherein the natural colour composition comprises: a) a first part configured to be applied to hair, comprising at least one compound selected from the group consisting of basic salts, organic bases, organic swelling agents; and a natural dye; and b) a second part configured to be applied to hair subsequent to application of the first part, comprising an inorganic metal salt based mordanting agent, wherein, the natural colour composition exhibits excellent colour coverage and wash off resistance. ### Claim 2 (depends on 1) The two-part natural colour composition as claimed in claim 1, further comprising a hair cleaning agent selected from lauryl sulfate, sodium laureth sulfate, polyoxyethylene derivatives, decyl glucoside, and lauryl glucoside. ### Claim 3 (depends on 1) The two-part natural colour composition as claimed in claim 1, further comprising a thickener selected from xanthan gum, quarternized guar and cellulosic gums in the form of gel. ### Claim 4 (depends on 1) The two-part natural colour composition as claimed in claim 1, further comprising: a conditioning and a colour protective agent selected from the group consisting of polyquaternium 113, polyquaternium 80, acrylamide copolymer, microbial protein lysates, hydolysable proteins; and a hair shine promoting ingredient selected from the group consisting of a propoxylated methyl glucose ether, fancorsil, and mixtures thereof. ### Claim 5 (depends on 1) The two-part natural colour composition as claimed claim 1, wherein the basic salt is selected from the group consisting of organic and inorganic oxides, carbonates, silicates, and bicarbonates. ### Claim 6 (depends on 5) The two-part natural colour composition as claimed in claim 5, wherein the basic salt is an alkali or alkaline earth carbonate. ### Claim 7 (depends on 1) The two-part natural colour composition as claimed in claim 1, wherein the mordanting agent is selected from the group consisting of Ferrous Sulfate, Ferrous Chloride, Ferric Chloride, Ferrous Oxide, Magnesium Carbonate, Manganese Sulfate, Manganese Gluconate, Zinc Sulphate, Zinc Chloride, Zinc Nitrate, Zinc Oxide, Copper Sulphate, Copper Nitrate, Copper Chloride, Copper Oxide, Magnesium Sulphate, Magnesium Nitrate, Magnesium Chloride, Magnesium Oxide, Magnesium carbonate, Sodium Chloride, Sodium bicarbonate, Sodium Carbonate, Cobalt Nitrate, Tin Chloride, Barium Chloride, Lead Nitrate, potassium tellurate, ferrous gluconate and mixtures thereof. ### Claim 8 (depends on 1) The two-part natural colour composition as claimed in claim 1, wherein the dye is selected from the group consisting of a non-oxidised logwood extract, an oxidised logwood extract, tannins, Benzoquinones, naphthoquinones, anthroquinones, carotenoids, indigo, indigo carmine, rubiethyric acid, purpuroxanthin, rubiadin, morindanigrin, munjistin, morindadiol, carotene, crocentin, bixin, canthaxanthin, lycopene, capsanthin, apocarotenal, xanthophyll, curcumin, morin, malclurin, luteolin, apigenin, fukugetin, datiscetin, kaempferol, rhamnocitrin, rhamnethin, zanthorhamnin, isorhamnetin, rharmazin, quercetin, rutin, gossypetin, butin, rotterin, chlorophyll A & B, catechin, fisetin, lapachol, juglone, alkannin, alkannan, deoxysantalin, atromentin, awobamin, riboflavin, anthocyanin, lawsone, embilica extract, carajuirin, dracorbohdin, berberine, betanin orcein, xanthone, naphthalene, alfalfa extract, black tea extract, green tea extract, white tea extract, red sandalwood, and mixtures thereof. ### Claim 9 (depends on 1) The two-part natural colour composition as claimed in claim 1, wherein the dye is selected from the group consisting of plant extracts of Haematoxylon campechianum, Haematoxylon brasiletto, Caesalpinia echinata, Caesalpinia sappan, Caesalpinia spinose, Caesalpina brasiliensis, Rubia cordifolia, Indigofera tinctora, Lawsonia sp, Terminaha chebula, and mixtures thereof. ### Claim 10 (depends on 1) The two-part natural colour composition as claimed in claim 1, wherein the natural hair composition further comprises a penetration aiding agent selected from the group consisting of organic ethers, aliphatic alcohols, aromatic/polyhydric alcohols and aldehydes, organic acids and oxones. ### Claim 11 (depends on 1) The two-part natural colour composition as claimed in claim 1, wherein the natural colour composition comprises: a) a basic salt in range of 0.5% to 8% by weight and a natural dye in range of 0.1% to 20% by weight. b) an inorganic metal salt based mordanting agent in range of 0.01% to 10% by weight. ### Claim 12 (depends on 1) The two-part natural colour composition as claimed in claim 1, wherein the natural colour composition exhibits wash-off resistance for 10 or more washes. ### Claim 13 (depends on 1) The two-part natural colour composition as claimed in claim 1, wherein the natural dye is: a logwood extract; or a mixture of a logwood extract and at least one of a henna extract, an indigo extract, and a madder extract. ### Claim 14 (depends on 10) The two-part natural colour composition as claimed in claim 10, wherein the penetration aiding agent is lactic acid or benzyl alcohol. ### Claim 15 A two-part natural colour composition containing two parts, wherein: a) a first part contains a natural dye comprising a logwood extract, alone or in combination with at least one of a henna extract, an indigo extract, and a madder extract; and at least one compound selected from the group consisting of basic salts, organic bases, and organic swelling agents; and b) a second part contains a metal salt based mordanting agent; wherein: the first part is configured to be applied to hair; and the second part is configured to be applied after the first part so as to modify a hair color produced by the natural dye. ### Claim 16 (depends on 15) The two-part natural colour composition as claimed in claim 15, wherein the basic salts are selected from the group consisting of organic and inorganic oxides, carbonates, silicates, bicarbonates and carboxyl amine compounds. ### Claim 17 A method for applying a two-part natural hair colour composition to hair, wherein the two-part natural hair colour composition comprises: a first part comprising an aqueous or alcoholic solution of dye and at least one compound selected from the group consisting of basic salts, organic bases, and organic swelling agents; wherein the dye comprises a logwood extract, alone or in combination with at least one of a henna extract, an indigo extract, and a madder extract; and a second part comprising an aqueous or alcoholic solution of a metal salt based mordanting agent; wherein the method comprises: a) applying the first part of the two-part natural hair colour composition to the hair; b) applying the second part of the two-part natural hair colour composition to the hair 30 minutes to 120 minutes after application of the first part of the two-part natural hair colour composition; and c) allowing the mordanting agent in the second part of the two-part natural hair colour composition to form a color-modifying complex with the dye in the first part of the two-part natural hair colour composition.