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US 11,891,503 B2Granted
Non-sticky, soft and transparent styrenic thermoplastic elastomers
AssigneeIneos Styrolution Group GmbH
InventorsMichiel Verswyvel, Norbert Niessner, Eike Jahnke, Daniel Wagner, Konrad Knoll
Life of this patent
Estimating the term…
Abstract
Thermoplastic elastomer compositions can be use for medical applications, Comprising: a) 97.1 to 90.9 wt.-% star-shaped block copolymer A with identical arms of the structure [S1-(S/B)k-(S/B)I-(S/B)m-S2]n-X, where S1 and S2 are vinylaromatic hard polymer and S/B are soft random vinylaromatic/diene copolymer blocks; X is a coupling center; and b) 2.9 to 9.1 wt.-% plasticizer B.
Claims17
A thermoplastic elastomer composition comprising components a), b), and c):
- a) 97.1 to 90.9 wt.-% of at least one star-shaped block copolymer A of the structure
- [S1-(S/B)k-(S/B)l-(S/B)m-S2]n-X (I),
- where S1 and S2 are polymer blocks made from at least one vinylaromatic monomer and S/B are random copolymer blocks made from at least one vinylaromatic monomer and at least one diene forming a soft phase;
- X is a coupling center derived from a polyfunctional coupling agent;
- b) 2.9 to 9.1 wt.-% of at least one plasticizer B;
- and
- c) 0 to 2 wt.-% of further additives C;
- wherein the sum of components a), b) and c) is 100 wt.-%;
- the arms S1-(S/B)k-(S/B)l-(S/B)m-S2 are identical;
- the proportion of the blocks S1 and S2 (forming a hard phase), based on the entire block copolymer A, is from 24 to 40 wt.-%;
- the vinylaromatic monomer/diene (=S/B) ratio of all of the blocks (S/B) is from 1/0.45 to 1/2.5;
- the S/B-ratio of the blocks (S/B)k, (S/B)l and (S/B)m is different from each other;
- the S/B-ratio of the blocks (S/B)k and (S/B)m is lower than the S/B-ratio of the block(s) (S/B)l;
- the weight ratio of blocks S2/S1 is from 0.1 to 0.8;
- the weight average molar mass Mw of the block copolymer A is from 200,000 to 350,000 g/mol;
- n is a natural number from 3 to 8;
- k and m are each 1;
- and
- l is a natural number of at least 1.
16 more elements
Dependencies are inferred from the claim text.