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US 11,891,354 B2Granted
Tricyclodecane dimethanol composition and preparation method of the same
AssigneeSK Chemicals Co., Ltd.
InventorsHee Il Chae, Ju-Sik Kang, Jeong Ho Park, Song Lee, Yu Mi Chang
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Abstract
Provided are a tricyclodecane dimethanol composition which may be suitably used in preparing a polyester resin exhibiting excellent solvent resistance and chemical resistance when forming a coating film and having excellent solubility in organic solvents or water, and a preparation method thereof.
Claims11
A composition comprising tricyclodecane dimethanol;
- and
- one or more of C11-12 diol compounds represented by the following Formula 1-1 and Formula 1-2,
- wherein the total content of the C11-12 diol compounds is 10% by weight to 20% by weight:
- in Formula 1-1,
- R1 and R2 are each independently hydrogen or methyl, provided that both R1 and R2 being methyl is excluded,
- in Formula 1-2,
- n is 3 or 4,
- when n is 3, R3 is hydrogen or methyl, and
- when n is 4, R3 is hydrogen.
6 more elements
A method of preparing a composition comprising tricyclodecane dimethanol;
- one or more of C11-12 diol compounds represented by the following Formula 1-1 and Formula 1-2, wherein the total content of the C11-12 diol compounds is 10% by weight to 20% by weight, the method comprising the steps of:
- performing a hydroformylation reaction by introducing a catalyst composition including a rhodium-containing catalyst compound and an organophosphorus compound into a reactor, and by adding dropwise dicyclopentadiene under a mixed gas of hydrogen and carbon monoxide;
- and
- performing a hydrogenation reaction of tricyclodecane dialdehyde obtained by the hydroformylation reaction in the presence of a hydrogenation catalyst,
- wherein the dicyclopentadiene includes 4% by weight to 20% by weight of co-dimers of C4-5 diene and cyclopentadiene:
- in Formula 1-1,
- R1 and R2 are each independently hydrogen or methyl, provided that both R1 and R2 being methyl is excluded,
- in Formula 1-2,
- n is 3 or 4,
- when n is 3, R3 is hydrogen or methyl, and
- when n is 4, R3 is hydrogen.
8 more elements
Dependencies are inferred from the claim text.