Lithiated cyclodextrin metal organic frameworks and methods of making and using the same
AssigneesNorthwestern University, King Abdulaziz City for Science and Technology (KACST)
InventorsJames Fraser Stoddart, Hasmukh A. Patel, Zhichang Liu, Siva Krishna Mohan Nalluri
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Abstract
Disclosed herein are lithiated cyclodextrin metal organic frameworks and method of making and using the same. A metal organic framework comprising a coordinated network of repeating units extending in three dimensions, wherein the repeating unit comprises a cyclodextrin, a first coordinating metal cation, and a second coordinating metal cation.
Claims16
A metal organic framework comprising a coordinated network of repeating units extending in three dimensions, wherein the repeating unit comprises a cyclodextrin and a metal salt component comprising Li+ and further comprising K+.
The metal organic framework of claim/i further comprising an adsorbed gas.
A method for preparing a metal organic framework, the method comprising:
- (a) providing a solution comprising a cyclodextrin, a metal salt component, and a first solvent and
- (b) adding a second solvent to the solution to prepare the metal organic framework,
- wherein the metal salt component comprises Li+ and K+ and
- wherein the cyclodextrin, Li+, or K+ have a lower solubility in the second solvent than the first solvent.
Dependencies are inferred from the claim text.