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US 11,884,987 B2Granted
Galvannealed steel sheet
AssigneeArcelorMittal
InventorsDavid Zapico Alvarez, Florence Bertrand, Joris Giroux
Life of this patent
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Abstract
A method for the manufacture of a galvannealed steel sheet including the provision of a specific steel sheet, a recrystallization annealing with specific heating, soaking and cooling sub-steps using an inert gas, a hot-dip galvanizing and an alloying treatment; the galvannealed steel sheet and the use of the galvannealed steel sheet.
Claims19
A method for manufacturing a galvannealed steel sheet, the method comprising:
- A. providing a steel sheet having the following chemical composition in weight percent:
- 0.05≤C≤0.20%,
- 1.5≤Mn≤3.0%,
- 0.10≤Si≤0.45%,
- 0.10≤Cr≤0.60%,
- Al≤0.20%,
- V<0.005%,
- 0≤P<0.04%,
- 0≤Nb≤0.05%,
- 0≤B≤0.003%,
- 0≤Mo≤0.020%,
- 0≤Ni≤0.1%,
- 0≤Ti≤0.06%,
- 0≤S≤0.01%,
- 0≤Cu≤0.1%,
- 0≤Co≤0.1%,
- 0≤N≤0.01%,
- a remainder of the composition being made of iron and inevitable impurities resulting from processing;
- B. recrystallization annealing the steel sheet in a full radiant tube furnace comprising a heating section, a soaking section, and a cooling section, and optionally an equalizing section, the recrystallization annealing including the following sub-steps:
- i. heating the steel sheet from ambient temperature to a temperature T1 between 700 and 900° C. in the heating section having an atmosphere A1 including from 0.1 to 15% by volume of H2 and an inert gas with a dew point DP1 between −18° C. and +8° C.,
- ii. soaking the steel sheet from T1 to a temperature T2 between 700 and 900° C. in the soaking section having an atmosphere A2 identical to A1 with a dew point DP2 equal to DP1, and
- iii. cooling the steel sheet from T2 to T3 between 400 and 700° C. in the cooling section having an atmosphere A3 including from 1 to 30% H2 by volume and an inert gas with a dew point DP3 below or equal to −30° C., and
- iv. optionally, equalizing the steel sheet from a temperature T3 to a temperature T4 between 400 and 700° C. in the equalizing section having an atmosphere A4 including from 1 to 30% H2 by volume and an inert gas with a dew point DP4 below or equal to −30° C.,
- C. hot-dip galvanizing of the annealed steel sheet in a zinc bath;
- and
- D. alloying the galvanized annealed steel sheet, the alloying performed at a temperature T5 between 460 and 600° C. during a time t5 between 1 and 45 seconds.
23 more elements
Dependencies are inferred from the claim text.