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US 11,884,847 B2Granted
Highly stretchable adhesive silicone compositions and uses thereof as sealing/bonding agents
AssigneeElkem Silicones USA Corp.
InventorsRemi Thiria, Brian Price, Chris Carpen, Phylandra Gaither
Life of this patent
Estimating the term…
Abstract
A curable silicone adhesive having improved elongation-at-break and adhesive properties to various substrates, in particular synthetic textiles used in the manufacture of air bags, to be used, for example, as a joint sealer. These silicone compositions provide excellent adhesive properties such as peel strength and cohesive failure when used to seal joints/seams between two pieces of textile fabric. Airbag fabrics using such novel addition curable adhesive silicone compositions are also provided.
Claims20
A curable silicone composition X comprising:
- A) at least one alkenyl group-containing organopolysiloxane A having at least two silicon-bonded C2 to C20 alkenyl groups per molecule,
- (B) at least one diorganohydrogensiloxy-terminated diorganopolysiloxane chain extender CE,
- (C) at least one diorganoalkenylsiloxy-terminated diorganopolysiloxane gum crosslinker Alk-XL containing at least 3 silicon-bonded C2 to C20 alkenyl groups per molecule,
- (D) optionally, at least one organosilicon crosslinker H-XL containing at least 3 silicon-bonded hydrogen atoms per molecule,
- (E) at least one addition reaction catalyst C,
- (F) at least one reinforcing mineral filler F1,
- (G) optionally, at least one complementary filler F2,
- (H) optionally, at least one cure rate modifier G,
- (I) optionally, at least one rheology modifier H,
- (J) optionally, at least one adhesion promoter I, and
- (K) optionally, at least one functional additive for conferring specific properties J;
- wherein the at least one diorganoalkenylsiloxy-terminated diorganopolysiloxane gum crosslinker Alk-XL containing at least 3 silicon-bonded C2 to C20 alkenyl groups per molecule has a total alkenyl content of from 0.02 to 0.10 weight %;
- and
- wherein the amounts of the alkenyl group-containing organopolysiloxane A, the diorganohydrogensiloxy-terminated diorganopolysiloxane CE, the diorganohydrogensiloxy-terminated diorganopolysiloxane gum crosslinker Alk-XL, and the optional organosilicon crosslinker H-XL are determined such that:
- 1) The value of the ratio RHalk is 1.05<RHalk<1.40, wherein RHalk=nH/tAlk, and wherein:
- a) nH is the number of moles of hydrogen atom directly bonded to a silicon atom in the curable silicone composition X;
- and
- b) tAlk is the number of moles of alkenyl groups directly bonded to a silicon atom in the curable silicone composition X,
- 2) the % molar ratio RHCE is within the range of 90%≤RHCE≤100%, wherein RHCE=nHCE/(nHCE+nHXL)×100, and wherein:
- a) nHCE is the number of moles of hydrogen atom directly bonded to a silicon atom in the diorganohydrogensiloxy-terminated diorganopolysiloxane CE, and
- b) nHXL is the number of moles of hydrogen atom directly bonded to a silicon atom in the organosilicon crosslinker H-XL, and
- 3) the % molar ratio RAlkA is within the range of 80%≤RAlkA<95%, wherein RAlkA=(nAlkA/tAlk)×100, and wherein:
- a) nAlkA is the number of moles of alkenyl groups directly bonded to a silicon atom in the organopolysiloxane A, and
- b) tAlk is the number of moles of alkenyl groups directly bonded to a silicon atom in the curable silicone composition X.
21 more elements
Dependencies are inferred from the claim text.