Additives for protection of polymers against ultraviolet light
AssigneeB.G. Negev Technologies and Applications Ltd., At Ben-Gurion University
InventorsMoshe Gottlieb, Olga Iliashevsky, Yafa Yagen
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Abstract
The invention provides ultraviolet light absorber suitable for use as an additive in polymers, comprising particles of inorganic oxide having UV light-absorbing compound on their surface, wherein said UV light-absorbing compound is chemically bonded, either to a spacer provided on the surface of said particle, or directly to the surface of the particle. Process for preparing the additive absorber and a thermoplastic polymer (e.g., a film) comprising the absorber additive are also provided.
Claims18
A process of preparing an ultraviolet light absorber additive for protecting polymers from ultraviolet radiation, comprising providing silica particles having silanol groups (SiOH) on their surface;
- reacting the silanol groups with a vinyl compound of the formula (H2C═CH)iSi(OCjH2j+1)4−i wherein 1≤i≤3 and 1≤j≤3, thereby covalently attaching the vinyl compound to the silica surface via the surface silanol groups, thereby introducing onto the surface of the silica particles a first functional group which is a carbon-carbon double bond, reacting the so-formed inorganic oxide particles modified with the carbon-carbon double bond group with a spacer having a plurality of a second functional group,
- wherein the spacer is an organosilicon compound having silicon hydride (SiH) functional groups, wherein the number of SiH groups in the organosilicon compound is denoted by n, where n is an integer equal to or greater than 4, wherein one SiH group participates in a bond formation reaction with the carbon-carbon double bond group present on the surface of the silica particles, thus having n−1 SiH groups available for bond formation reaction with a UV light absorbing compounds;
- reacting the so-formed particles having n−1 SiH groups available for bond formation reaction, with a UV light absorbing compound;
- and isolating from the reaction mixture said ultraviolet light absorber additive.
Dependencies are inferred from the claim text.