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US 11,884,622 B2Granted
Tricyclodecane dimethanol composition and preparation method of the same
AssigneeSK Chemicals Co., Ltd.
InventorsHee Il Chae, Ju-Sik Kang, Jeong Ho Park, Song Lee, Yu Mi Chang
Life of this patent
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Abstract
Provided are a tricyclodecane dimethanol composition which may be usefully applied to the preparation of a high heat resistant polyester by reducing the content of impurities, and a preparation method thereof.
Claims11
A tricyclodecane dimethanol composition comprising:
- tricyclodecane dimethanol, and
- an ether compound represented by Formula 1 in an amount of 1% by weight or less,
- wherein Formula 1 is represented by:
- R1—CH2—O—CH2—R2,
- and wherein, in Formula 1, R1 and R2 are each independently selected from the group consisting of:
2 more elements
A method of preparing a tricyclodecane dimethanol composition comprising tricyclodecane dimethanol, and
- an ether compound represented by Formula 1 in an amount of 1% by weight or less,
- the method comprising the following steps of ii), iii), iv), and vi), and further comprising one or more of the following steps of i) and v):
- i) purifying dicyclopentadiene by performing a retro Diels-Alder reaction and a Diels-Alder reaction of dicyclopentadiene;
- ii) performing a hydroformylation reaction by introducing a catalyst composition including a rhodium-containing catalyst compound and an organophosphorus compound into a reactor, and by adding dropwise dicyclopentadiene under a mixed gas of hydrogen and carbon monoxide;
- iii) performing a hydrogenation reaction of the reaction mixture obtained after the step ii) in the presence of a hydrogenation catalyst;
- iv) removing the hydrogenation catalyst and the solvent from the reaction mixture obtained after the step iii);
- v) performing thin film evaporation of the reaction mixture obtained after the step iv);
- and
- vi) performing vacuum fractional distillation of the reaction mixture obtained after the step iv) or the step v),
- wherein Formula 1 is represented by:
- R1—CH2—O—CH2—R2,
- and wherein, in Formula 1, R1 and R2 are each independently selected from the group consisting of:
9 more elements
Dependencies are inferred from the claim text.