Synthetic polymer film provided with surface having sterilizing effect, method for manufacturing synthetic polymer film and sterilization method using surface of synthetic polymer film
AssigneeSharp Kabushiki Kaisha
InventorsTakahiro Nakahara, Hidekazu Hayashi
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Abstract
A synthetic polymer film (35), (36) having a surface which has a plurality of raised portions (35p), (36p), wherein a two-dimensional size of the plurality of raised portions is in a range of more than 20 nm and less than 500 nm when viewed in a normal direction of the synthetic polymer film, the surface having a microbicidal effect, and the synthetic polymer film includes a fluorine element in such a profile that a fluorine content is not constant in a thickness direction but is higher in a portion closer to the plurality of raised portions than in a portion farther from the plurality of raised portions.
Claims21
A synthetic polymer film having a first surface which has a plurality of raised portions, wherein:
- a two-dimensional size of the plurality of raised portions is in a range of greater than 20 nm and less than 500 nm when viewed in a normal direction of the synthetic polymer film, the first surface having a microbicidal effect;
- the synthetic polymer film includes a fluorine element in a profile that a fluorine content is not constant in a thickness direction but is higher in a first portion closer to the plurality of raised portions than in a second portion farther from the plurality of raised portions;
- the first portion includes a third portion that is formed from a first photocurable resin, the first photocurable resin including a fluorine-containing acrylic monomer, an acryloyl group-containing monomer, and no urethane acrylate monomer;
- the first portion further includes a fourth portion that is formed from the first photocurable resin and a second photocurable resin, the second photocurable resin including a urethane acrylate monomer;
- the second portion is formed from the second photocurable resin;
- the second portion and the fourth portion are in contact with each other;
- the entirety of the plurality of raised portions is included in the first portion;
- the entirety of the plurality of raised portions is included in the third portion;
- the third portion and the fourth portion are in contact with each other;
- and
- the fourth portion is between the third portion and the second portion in the thickness direction.
A synthetic polymer film having a first surface which has a plurality of raised portions, wherein:
- a two-dimensional size of the plurality of raised portions is in a range of greater than 20 nm and less than 500 nm when viewed in a normal direction of the synthetic polymer film, the first surface having a microbicidal effect;
- a logarithmic value of a value obtained by dividing a bacteria count after culturing for 24 hours on a polyethylene terephthalate (PET) film by a bacteria count after culturing for 24 hours on the first surface is more than 3.8;
- the synthetic polymer film includes a fluorine element in a profile that a fluorine content is not constant in a thickness direction but is higher in a first portion closer to the plurality of raised portions than in a second portion farther from the plurality of raised portions;
- the first portion includes a third portion that is formed from a first photocurable resin, the first photocurable resin including a fluorine-containing acrylic monomer, an acryloyl group-containing monomer, and no urethane acrylate monomer;
- the first portion further includes a fourth portion that is formed from the first photocurable resin and a second photocurable resin, the second photocurable resin including a urethane acrylate monomer;
- the second portion is formed from the second photocurable resin;
- the second portion and the fourth portion are in contact with each other;
- the entirety of the plurality of raised portions is included in the first portion;
- the synthetic polymer film includes, at a second surface opposite to the first surface, a nitrogen element which is not a constituent of a tertiary amine in a proportion of not less than 1.035 at %;
- the entirety of the plurality of raised portions is included in the third portion;
- the third portion and the fourth portion are in contact with each other;
- and
- the fourth portion is between the third portion and the second portion in the thickness direction.
Dependencies are inferred from the claim text.