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US 11,873,226 B2Granted
Sheet-like particles of zeolite and method for producing same
AssigneeJapan Science and Technology Agency
InventorsYoshiaki Uchida, Koki Sasaki, Norikazu Nishiyama
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Abstract
The invention provides a method for producing sheet-like particles of zeolite that cannot be obtained by a top-down method, and provides sheet-like particles of zeolite having an 8-membered oxygen ring structure obtained by the method. A thickness of the sheet-like particles is 1 nm to 100 nm, and an aspect ratio (maximum width/thickness in particles) of the sheet-like particles is 100 or more.
Claims8
A method for producing sheet-like particles of zeolite, comprising:
- a first step which comprises
- forming a bilayer in a solvent,
- forming a hyper-swollen lamellar phase of the bilayer by adding, in the solvent, an aluminum atomic source, and at least one atomic source selected from the group consisting of a silicon atomic source and a phosphorus atomic source, and
- forming sheet-like particles of a precursor of zeolite between two monomolecular layers, wherein the two monomolecular layers constitute the bilayer and are formed from amphiphilic molecules;
- and
- a second step of bringing the sheet-like particles of the precursor of zeolite into contact with gaseous water in a container to form the sheet-like particles of zeolite,
- wherein a thickness of the sheet-like particles of the zeolite is 1 nm or more and 100 nm or less;
- an aspect ratio (maximum width/thickness in particles) of the sheet-like particles of the zeolite is 100 or more;
- the solvent contained in a whole system in the formation of the hyper-swollen lamellar phase is a mixed solvent containing a hydrocarbon solvent and water, wherein the whole system in the formation of the hyper-swollen lamellar phase means any components which are mixed in order to form the super-swollen lamellar phase and include solutes and solvents;
- and
- a mass ratio of the hydrocarbon-containing solvent and water in the mixed solvent is 85:15 to 99.99:0.01.
8 more elements
Dependencies are inferred from the claim text.