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US 11,851,444 B2Granted
Redox active materials, processes and uses thereof
AssigneeKasis Environmental Ltd.
InventorsAndrew S. Grant, Travis Osmond
Life of this patent
Estimating the term…
Abstract
The present disclosure relates to redox active materials, such as the compound of formula (I), comprising at least one 2,5-dithio-7-azabicyclo(2.2.1)heptane unit connected to a surface thereof, as well as processes for making said redox active materials. The present disclosure relates to a method for recovering a metal, comprising reacting a metal in oxidized state with said redox active material. The present disclosure relates to uses of these redox active materials in sensors, electronic materials and for extracting metals.
Claims19
A redox active material having formula I:
- wherein X is a solid phase carrier chosen from colloidal silica, silica, glass, glass wool, cellulose, pulp-derived cellulose, microcrystalline cellulose, nanocellulose, cotton, paper, chitin, chitosan, agarose, starch, alumina, diatomaceous earth, peptide, protein, (aminomethyl)polystyrene, (2-aminoethyl)polystyrene, poly(ethyleneimine), polyallylamine, polyesters from modified 5-aminoisophthalic acid, polyamides from modified 5-aminoisophthalic acid, and mixtures thereof, wherein said peptide or said protein comprises at least one lysine residue;
- R is a linker or a chemical bond;
- n is any integer greater than 0;
- and R′ is chosen from hydrogen, C1-C20 alkyl, C3-C8 cycloalkyl, C6-C12 aryl, C1-C12 heteroaryl, C1-C12 heterocyclyl and C6-C20 aralkyl,
- said alkyl, cycloalkyl, heteroaryl and heterocyclyl being unsubstituted or substituted with at least one substituent chosen from a halogen atom, —OH, —SH, —OMe, —SMe, —SPh, C1-C6 alkoxy, C1-C8 alkyl, C2-C8 alkenyl, C2-C8 alkynyl, C1-C6 aminoalkyl, C6-C20 aralkyl, C6-C12 aryl, C3-C8 cycloalkyl, C1-C12 heteroaryl, C1-C12 heterocyclyl and C1-C6 hydroxyalkyl,
- an enantiomer thereof, a mixture of said redox active material having Formula I and said enantiomer thereof, diastereoisomers thereof, stereoisomers thereof and epimers thereof.
3 more elements
Dependencies are inferred from the claim text.