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US 11,851,402 B2Granted
Specific dehydrogenation process (I)
AssigneeDsm IP Assets B.V.
InventorsWerner Bonrath, Marc-André Mueller, Bettina Wuestenberg
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Abstract
The present invention relates to a new dehydrogenation process of specific compounds.
Claims12
A process for the production of a compound of formula (II):
- wherein
- R is —CH═O or —CH2OCOR′, wherein R′ is a —C1-C16 alkyl group,
- wherein
- the process comprises conducting in the presence of at least one oxidative reactant and in the presence of at least one additive compound a selective dehydrogenation of a compound of formula (I):
- wherein
- R has the same meanings as in the compound of formula (II), wherein
- the at least one oxidative reactant is a compound of formula (III):
- wherein
- R1 is —CN, —Cl or —F,
- R2 is —CN, —Cl or —F,
- R3 is —H, —CH3, —Cl or —F, and
- R4 is —H, —CH3, —Cl or —F.
9 more elements
The process according to anyone of the preceding claims, wherein the process comprises conducting the selective dehydrogenation at a temperature of 0° C.—120° C.
A compound of formula (Ia):
A compound of formula (Ib):
Dependencies are inferred from the claim text.