A method for reducing deposition of thermal decomposition products on a wall of an article containing a hydrocarbon fluid at temperatures above 105° C. comprising, depositing an anti-coking coating on a first surface of the wall of the article that is wetted by the hydrocarbon fuel, the anti-coking coating comprising a copper salt, a silver salt, or a combination thereof, the hydrocarbon fluid contacting and flowing across the anti-coking coating, wherein the copper salt comprises copper (II) sulfate, copper (II) nitrate, copper (II) chloride, copper (II) chloride anhydrous, copper (II) chloride dihydrate, or combinations thereof.