Triazine ring-containing polymer, and thermoplastic resin, article, and optical part including same
AssigneesSamsung Electronics Co., Ltd., Osaka Gas Chemicals Co., Ltd.
InventorsNobuji Sakai, Hiroko Endo, Yukika Yamada, Eigo Miyazaki, Rie Yasuda, Shinsuke Miyauchi
Life of this patent
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Abstract
A triazine ring-containing polymer having a high refractive index and a low birefringence, and being capable of being subjected to injection molding, wherein the polymer having a repeating unit of *-[A-B-]-*, including a structural unit A derived from a triazinedithiol compound, and a structural unit B including an aromatic hydrocarbon group; and a thermoplastic resin, a thermoplastic article, and an optical part including the polymer.
Claims20
A triazine ring-containing polymer comprising a repeating unit represented by General Formula 1:
- *-[A-B-]-* General Formula 1
- wherein, in General Formula 1,
- A is represented by General Formula 2,
- B is represented by any one of General Formulae 3-1 to 3-3, and
- * indicates a point linked to another structural unit or atom;
- General Formula 2
- wherein, in General Formula 2,
- L is a single bond or a linking group,
- R1 is a group comprising an oxygen atom, sulfur atom, nitrogen atom, selenium atom, or a combination thereof, and
- * indicates a point linked to another structural unit or atom;
- General Formulae 3-1 to 3-3
- wherein, in General Formula 3-1,
- R2a and R2b are each independently a C1 to C10 alkylene group, or an alkylene oxide group of formula —(O—CmH2m)n—, wherein, m is an integer ranging from 1 to 4, and n is an integer ranging from 1 to 3;
- Z1 and Z2 are independently hydrogen, or a fused aromatic hydrocarbon group, wherein at least one of Z1 or Z2 is the fused aromatic hydrocarbon group, wherein, R3a, R3b, R4a and R4b are each independently a substituent, n1 and n2 are each independently 0, 1, or 2, m1 and m2 are each independently an integer of 0, or any one of 1 to 4 and
- * indicates a point linked to another structural unit or atom;
- wherein, in General Formula 3-2,
- Z3 and Z4 are each independently an aromatic hydrocarbon group,
- R5a, R5b, R6a and R6b are each independently a substituent,
- R7a and R7b are each independently a C1 to C10 alkylene group, or an alkylene oxide group of formula —(O—CmH2m)n—, wherein, m is an integer ranging from 1 to 4, and n is an integer ranging from 1 to 3;
- o1 and o2 are each independently an integer of 0, or any one of 1 to 4, and p1 and p2 are each independently an integer of 0, or any one of 1 to 4, and
- * indicates a point linked to another structural unit or atom;
- and
- wherein, in General Formula 3-3,
- R8a and R8b are each independently a substituent,
- R9a and R9b are each independently a C1 to C10 alkylene group, or an alkylene oxide group of formula —(O—CmH2m)n—, wherein, m is an integer ranging from 1 to 4, and n is an integer ranging from 1 to 3,
- q1 and q2 are each independently an integer of 0, or any one of 1 to 4;
- and
- * indicates a point linked to another structural unit or atom.
A triazine ring-containing polymer comprising a repeating unit represented by General Formula 1:
- General Formula 1
- *-[A-B-]-*
- wherein, in General Formula 1,
- A is represented by General Formula 2,
- B is represented by any one of General Formulae 3-1 to 3-3, and
- * indicates a point linked to another structural unit or atom;
- General Formula 2
- wherein, in General Formula 2,
- L is a single bond, a C1 to C6 alkylene group, a divalent C6 to C30 aromatic hydrocarbon group, or an aromatic hydrocarbon linking group in which two or more C6 to C30 aromatic hydrocarbon groups are linked to each other by a single bond, a C1 to C6 alkylene group, or an atom of oxygen, sulfur, or selenium
- R1 is a group comprising an oxygen atom, sulfur atom, nitrogen atom, selenium atom, or a combination thereof, and
- * indicates a point linked to another structural unit or atom;
- General Formulae 3-1 to 3-3
- wherein, in General Formula 3-1,
- R2a and R2b are each independently —CH2 —, —CH2CH2—, —CH2CH2CH2—, —CH(CH3)CH2—, —CH2CH(CH2CH3)CH2CH2CH2CH2—, —O—CH2—, —O—CH2CH2—, —O—CH2CH2CH2—, —O—CH(CH3)CH2—, —(O—CH2)2—, or —(O—CH2CH2)2—
- Z1 and Z2 are independently hydrogen, or a fused aromatic hydrocarbon group, wherein at least one of Z1 or Z2 is the fused aromatic hydrocarbon group, wherein, R3a, R3b , R4a and R4b are each independently a substituent, n1 and n2 are each independently 0, 1, or 2, m1 and m2 are each independently an integer of 0, or any one of 1 to 4, and
- * indicates a point linked to another structural unit or atom;
- wherein, in General Formula 3-2,
- Z3 and Z4 are each independently an aromatic hydrocarbon group,
- R5a, R5b, R6a and R6b are each independently a substituent,
- R7a and R7b are each independently —CH2—, —CH2CH2—, —CH2CH2CH2—, —CH(CH3)CH2—, —CH2CH(CH2CH3)CH2CH2CH2CH2—, —O—CH2—, —O—CH2CH2—, —O—CH2CH2CH2—, —O—CH(CH3)CH2—, —(O—CH2)2—, or —(O—CH2CH2)2—,
- o1 and o2 are each independently an integer of 0, or any one of 1 to 4, and p1 and p2 are each independently an integer of 0, or any one of 1 to 4, and
- * indicates a point linked to another structural unit or atom;
- and
- wherein, in General Formula 3-3,
- R8a and R8b are each independently a substituent,
- R9a and R9b are each independently —CH2—, —CH2CH2—, —CH2CH2CH2—, —CH(CH3)CH2—, —CH2CH(CH2CH3)CH2CH2CH2CH2—, —O—CH2—, —O—CH2CH2—, —O—CH2CH2CH2—, —O—CH(CH3)CH2—, —(O—CH2)2—, or —(O—CH2CH2)2—,
- q1 and q2 are each independently an integer of 0, or any one of 1 to 4;
- and
- * indicates a point linked to another structural unit or atom.
Dependencies are inferred from the claim text.