Polyamine additive

A water dilutable polyamine additive comprising the polymerization product of free radically polymerizable monomers into repeating units of a polyamine wherein:

• a) from 30-90 wt. % of repeating units are from a free radically polymerizable tertiary amine monomer(s) comprising Formula A1 or A2
• wherein Ra is O or NRk, Rb is a C1 to C6 alkylene, Re is a C1-C4 alkyl, Rf is a C1-C4 alkyl, Rg is H or methyl or ethyl and Rh is H or methyl or ethyl, Rk is H, a C1-C4 alkyl, or a C1-C4 acyl group, A′ is poly(oxy-C2H4 and/or C3H6 alkylene) homopolymer or copolymer having a number average molecular weight of 88-348 g/mole, m is 2 or 3, Ri is selected from a group consisting of hydrogen, phenyl group, benzyl group, and a C1-C12 alkyl group if it is not linked directly to Rj to form an alkylene group, Rj is selected from a group consisting of hydrogen, a C1-C4 alkyl group, if it is not linked directly to Ri, and optionally Ri and Rj together are covalently bonded to each other to form a C4 or C5 alkylene group forming a 5 or 6 membered ring with the C atom to which they are attached, with
• b) from 10-60 wt. % of repeating units are from a poly(alkylene oxide) monomer B of the formula
• wherein Rp is a poly(alkylene oxide) having a number average molecular weight from about 88 to about 1200, wherein said poly(alkylene oxide) has 2 or 3 or 4 carbons per alkylene group, Rq is H or C1-C8 alkylene group;
• and Rr is H or methyl or ethyl;
• c) from about 5 to about 60 wt. % of repeating units are from other free radically polymerizable monomers other than monomers A1, A2 and B, and the polyamine additive has a number average molecular weight from 10,000 and 500,000 Daltons based on GPC molecular weight determinations using polystyrene standards.