Aziridine polymers whose chemical structural changes are induced by mechanical force
AssigneeKorea University Research and Business Foundation
InventorsHyo Jae Yoon, Sangmin Jung
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Abstract
Disclosed are new polymeric materials that respond to a mechanical force. The novel polymeric compounds contain an isomer of aziridine, a three-membered N-heterocyclic compound. Also disclosed are methods for preparing the polymeric compounds. Mechanical force-induced cycloaddition of aziridines as mechanophores yields stereospecific products without covalent bond cleavage of aziridines. That is, a mechanical force makes the mechanochemical products stereospecific. The stereospecific products prepared from the isomeric mechanophores by a mechanical force can be widely used in various industrial fields, including new materials.
Claims14
A polymeric compound comprising a repeating unit represented by Formula 1-1:
- wherein R is
- and n is an integer from 123 to 125, and
- a repeating unit represented by Formula 1-2:
- wherein m is an integer from 123 to 125.
A polymeric compound comprising a repeating unit represented by Formula 2-1:
- wherein R is
- and n is an integer from 108 to 110, and
- a repeating unit represented by Formula 2-2:
- wherein m is an integer from 108 to 110.
Dependencies are inferred from the claim text.