Process for producing optical molding materials
AssigneeRohm Co., Ltd.
InventorsSteffen Krill, Belaid Ait Aissa, Florian Zschunke, Gerhard Kölbl, Rüdiger Carloff
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Abstract
A process can be used for producing optical molding materials on the basis of methyl methacrylate (MMA). The MMA produced by an optimized method and the molding materials feature in particular a very low yellowness index. This MMA has been produced by direct oxidative esterification of methacrolein. An optimized workup of the reactor output from the oxidative esterification of methacrolein can be used for removing particularly discoloring byproducts. This process moreover has the advantage that fewer demands are placed on plant apparatus configuration.
Claims17
A method for producing a transparent or colored article, the method comprising:
- molding an alkyl methacrylate resin comprising an alkyl methacrylate into a transparent or colored article, wherein when the article is transparent, it is selected from at least one article selected from the group consisting of an optically conductive sheet, a headlight lens, a headlight cover, a cover for a light source, a display cover, a noise barrier, and a construction material for a greenhouse,
- wherein the alkyl methacrylate is produced by a process comprising:
- a. producing methacrolein in a reactor I,
- b. oxidatively esterifying the methacrolein in the presence of an alcohol, oxygen, and a heterogeneous noble metal-containing catalyst, at a water content between 0.1% and 10% by weight and a pH between 5 and 8 in at least one reactor II, to obtain a reactor output,
- c. after-treating the reactor output from the at least one reactor II in a reactor to obtain a crude alkyl methacrylate, and
- d. isolating and purifying the crude alkyl methacrylate from the reactor III,
- wherein the alkyl methacrylate comprises dimethoxyisobutene (DMIB) and methyl isobutyrate, and has a DMIB content of less than 300 ppm and a methyl isobutyrate content of less than 600 ppm, and
- wherein in process step c, in the reactor III, a water content is at least 0.5% by weight higher than in the at least one reactor II.
Dependencies are inferred from the claim text.