Bio-lubricant with high viscosity and method
AssigneeKing Abdullah University of Science and Technology
InventorsRibhu Gautam, Tsu Fang Hong, Subram Maniam Sarathy
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Abstract
A bio-lubricant composition includes a first component that includes a first triglyceride, which is part of a cooking oil; a second component that includes a first epoxidized triglyceride; a third component that includes a hydroxylated triglyceride; a fourth component that includes a first fatty acid ester moiety; a fifth component that includes a first epoxidized fatty acid ester; and a sixth component that includes a hydroxylated fatty acid ester. A mixture of the first to sixth components at room temperature have a viscosity between 40 and 200 centipoise, and the composition is substantially free of free fatty acids.
Claims20
A bio-lubricant composition comprising:
- a first component that includes a first triglyceride, which is part of a waste cooking oil;
- a second component that includes a first epoxidized triglyceride;
- a third component that includes a hydroxylated triglyceride;
- a fourth component that includes a first fatty acid ester moiety;
- a fifth component that includes a first epoxidized fatty acid ester;
- and
- a sixth component that includes a hydroxylated fatty acid ester,
- wherein a mixture of the first to sixth components at room temperature has a viscosity between 40 and 200 centipoise, and
- wherein the composition is substantially free of free fatty acids.
A bio-lubricant composition comprising:
- a first component that includes a first triglyceride, which is part of waste cooking oil;
- a second component that includes a first epoxidized triglyceride, which originates from a second triglyceride, which is part of the waste cooking oil, wherein the second triglyceride has been epoxidated to obtain the first epoxidized triglyceride;
- a third component that includes a hydroxylated triglyceride, which originates from a third triglyceride of the waste cooking oil, wherein the third triglyceride was epoxidized to form a second epoxidized triglyceride and the second epoxidized triglyceride was hydroxylated to form the hydroxylated triglyceride;
- a fourth component that includes a first fatty acid ester moiety, which originates from a first free fatty acid of the waste cooking oil;
- a fifth component that includes a first epoxidized fatty acid ester, which originates from a second free fatty acid of the waste cooking oil, and the second free fatty acid was esterified to form a second fatty acid ester moiety and the second fatty acid ester moiety was epoxidated to form the first epoxidized fatty acid ester;
- and
- a sixth component that includes a hydroxylated fatty acid ester, which originates from a third free fatty acid of the waste cooking oil, and the third free fatty acid was esterified to form a third fatty acid ester moiety, the third fatty acid ester moiety was epoxidated to form a second epoxidized fatty acid ester, and the second epoxidized fatty acid was hydroxylated to form the hydroxylated fatty acid ester,
- wherein a mixture of the first to sixth components at room temperature has a viscosity between 40 and 200 centipoise, and
- wherein the composition is substantially free of free fatty acids.
A method for making a bio-lubricant composition from waste cooking oil, the method comprising:
- purifying the waste cooking oil with an activated biochar to obtain purified cooking oil, wherein the purified cooking oil includes triglycerides and free fatty acids;
- esterifying the purified cooking oil to transform substantially all the free fatty acids into fatty acid methyl ester moieties, wherein this step maintains a viscosity of the purified cooking oil when transformed into a first mixture of the triglycerides and the fatty acid methyl ester moieties;
- stabilizing a structure of the triglycerides and the fatty acid methyl ester moieties by epoxidation, which results in a second mixture of epoxidated triglycerides, epoxidated fatty acid esters, the triglycerides, and the fatty acid methyl ester moieties;
- and
- increasing the viscosity of the second mixture by opening epoxy rings with a hydroxylation process, which results in a third mixture of the triglycerides, the fatty acid methyl ester moieties, the epoxidated triglycerides, the epoxidated fatty acid esters, hydroxylated triglycerides, and hydroxylated fatty acid esters,
- wherein the third mixture at room temperature has a viscosity between 40 and 200 centipoise.
Dependencies are inferred from the claim text.