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US 11,767,227 B2Granted
Co-production of methanol and ammonia
AssigneeTopsoe A/S
InventorsPat A. Han, Mitra Heidarpanah
Life of this patent
Estimating the term…
Abstract
A plant for the co-production of methanol and ammonia from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units and water gas shift.
Claims6
A plant for co-producing methanol and ammonia from a hydrocarbon feedstock, comprising:
- a first methanol process line for carrying out a first reforming step and a first methanol conversion step to obtain a first effluent comprising methanol and a first gas effluent comprising hydrogen, nitrogen and unconverted carbon oxides;
- a second methanol process line for carrying out a second reforming step and a second methanol conversion step to obtain a second effluent comprising methanol and a second gas effluent comprising hydrogen, nitrogen and unconverted carbon oxides;
- an interconnecting synthesis line allowing fluid communication between the first and second methanol process lines, allowing a methanol synthesis gas from each of the two first and second reforming steps to be distributed to each of the first and second methanol conversion steps;
- a catalytic methanation stage for producing ammonia synthesis gas from the first gas effluent and the second gas effluent, the ammonia synthesis gas having a H2:N2 molar ratio of approximately 3:1;
- and
- an ammonia synthesis stage for catalytically converting the nitrogen and hydrogen of the ammonia synthesis gas to produce an effluent comprising ammonia and a purge-gas stream comprising hydrogen, nitrogen and/or methane,
- wherein the first reforming step of the first methanol process line and the second reforming step of the second methanol process line are each carried out in a respective primary reforming stage and a respective secondary reforming stage, wherein the hydrocarbon feedstock is steam reformed in the respective primary reforming stage to obtain a partially reformed gas and the partially reformed gas is then further reformed under addition of air in the respective secondary reforming stage to obtain the methanol synthesis gas.
4 more elements
Dependencies are inferred from the claim text.