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US 11,767,226 B2Granted
Co-production of methanol, ammonia and urea
AssigneeTopsoe A/S
InventorsPat A. Han, Mitra Heidarpanah
Life of this patent
Estimating the term…
Abstract
A process and plant for the co-production of methanol and ammonia together with urea production from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units and water gas shift. Carbon dioxide is removed from flue gas from reforming section and used to convert partially or fully all ammonia into urea.
Claims8
A plant for co-producing methanol, ammonia and urea from a hydrocarbon feedstock, comprising:
- a first methanol process line for carrying out a first reforming step and a first methanol conversion step to obtain a first effluent comprising methanol and a first gas effluent comprising hydrogen, nitrogen and unconverted carbon oxides;
- a second methanol process line for carrying out a second reforming step and a second methanol conversion step to obtain a second effluent comprising methanol and a second gas effluent comprising hydrogen, nitrogen and unconverted carbon oxides;
- an interconnecting synthesis line allowing fluid communication between the first and second methanol process lines, allowing a methanol synthesis gas from each of the two first and second reforming steps to be distributed to each of the first and second methanol conversion steps;
- a catalytic methanation stage for producing ammonia synthesis gas from the first gas effluent and the second gas effluent, the ammonia synthesis gas having a H2:N2 molar ratio of approximately 3:1;
- an ammonia synthesis stage for catalytically converting the nitrogen and hydrogen of the ammonia synthesis gas to produce an effluent comprising ammonia and a purge-gas stream comprising hydrogen, nitrogen and/or methane;
- and
- a urea plant for reacting at least part of the effluent comprising ammonia with at least part of a flue gas comprising CO2 from at least one of the first and second reforming steps to produce urea;
- wherein the first reforming step of the first methanol process line and the second reforming step of the second methanol process line are each carried out in a respective primary reforming stage and a respective secondary reforming stage, wherein the hydrocarbon feedstock is steam reformed in the respective primary reforming stage to obtain a partially reformed gas and the partially reformed gas is then further reformed under addition of air in the respective secondary reforming stage to obtain the methanol synthesis gas.
5 more elements
Dependencies are inferred from the claim text.