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US 11,760,765 B2Granted
Method for producing triarylorganoborates
AssigneeCovestro Intellectual Property GmbH & Co. KG
InventorsThomas Rölle, Horst Berneth, Dennis Hönel, Friedrich-Karl Bruder, Jürgen Kintrup
Life of this patent
Estimating the term…
Abstract
The invention relates to a process for preparing triaryl organoborates proceeding from organoboronic esters in the presence of an n-valent cation 1/n Kn+, comprising the anhydrous workup of the reaction mixture and the use of the triaryl organoborates obtained as co-initiator in photopolymer formulations, holographic media and holograms.
Claims10
Compounds of the formula (CC)
- in which
- R301 and R301′ are each independently an optionally branched C14- to C22-alkyl radical or are additionally defined as R302, with the proviso that T301 and R331 together and T302 and R332 together each contain at least 12 carbon atoms,
- R302 is a radical of the formulae
- T301 is a bridge having 2 to 16 carbon atoms, of which not more than one third may be replaced by O and/or NR400, where there must be at least 2 carbon atoms between O or NR200, and which may be arranged in the form of an optionally branched chain and/or a five- or six-membered ring,
- R331 is an optionally branched and/or optionally substituted C4- to C22-alkylene radical, a cyclopentylene, cyclohexylene or cycloheptylene radical, a C8- to C12-aryldialkylene radical, an arylene radical or heteroarylene radical optionally substituted by nonionic radicals, an optionally branched and/or optionally substituted C4- to C22-alkanedioxy radical, a cyclopentanedioxy, cyclohexanedioxy or cycloheptanedioxy radical, a C7- to C12-oxyarylalkoxy radical, C8- to C12-aryldi(alkyloxy) radical, a benzenedioxy radical or heteroaryldioxy radical optionally substituted by nonionic radicals, an optionally branched and/or optionally substituted C4- to C22-alkanediamino radical, a cyclopentanediamino, cyclohexanediamino or cycloheptanediamino radical, a C8- to C12-aminoarylalkylamino radical, a benzenediamino radical or heteroarylenediamino radical optionally substituted by nonionic radicals, an alkylene-cycloalkylene radical, alkanedicycloalkylene radical or alkanediarylene radical,
- T302 is a bridge having 1 to 16 carbon atoms which may be arranged in the form of an optionally branched chain and/or a five- or six-membered ring,
- R332 is an optionally branched and/or optionally substituted C1- to C22-alkylene radical, a cyclopentylene, cyclohexylene or cycloheptylene radical, a C8- to C12-aralkylene radical, an arylene or heteroarylene radical optionally substituted by nonionic radicals,
- A is NR401 or oxygen,
- R400 and R401 are independently hydrogen or C1- to C4-alkyl,
- R303, R304, R303′ and R304′ are independently an optionally branched and/or optionally substituted C1- to C5-alkyl radical,
- or
- R302 is a radical of the formulae
- T301, R331, T302, R332, R400, R401 and A have the definition given above, with the proviso that T301 and R331 together and T302 and R332 together each contain at least 12 carbon atoms,
- R301, R303 and R304 together with the N+ atom form an imidazole or pyridine ring substituted at least by one radical selected from C1- to C8-alkyl, C1- to C8-alkoxy, C5- to C7-cycloalkyl, benzyl or phenyl, and/or
- R301′, R303′ and R304′ together with the N+ atom form an imidazole or pyridine ring substituted at least by one radical selected from C1- to C8-alkyl, C1- to C8-alkoxy, C5- to C7-cycloalkyl, benzyl or phenyl,
- or
- R301 and R301′ are each independently an optionally branched C14- to C22-alkyl radical or are additionally defined as R302, with the proviso that T301 and R331 together and T302 and R332 together each contain at least 12 carbon atoms,
- R302 is a radical of the formulae
- and
- T301, R331, T302, R332, R400, R401 and A have the definition given above,
- R303 and R304 together form a —(CH2)4—, —(CH2)5— or —(CH2)2—O—(CH2)2— bridge, and/or
- R303′ and R304′ together form a —(CH2)4—, —(CH2)5— or —(CH2)2—O—(CH2)2— bridge, and
- R1 is an optionally hydroxyl- and/or alkoxy- and/or acyloxy- and/or halogen-substituted C1- to C22-alkyl, C3- to C22-alkenyl, C3- to C22-alkynyl, C5- to C7-cycloalkyl or C7- to C13-aralkyl radical and
- R4 is a C6- to C10-aryl radical optionally substituted by at least one radical selected from halogen, C1- to C4-alkyl, trifluoromethyl, C1- to C4-alkoxy, trifluoromethoxy, phenyl and phenoxy.
21 more elements
Dependencies are inferred from the claim text.