Emulsion shear bond enhanced cement
AssigneeSaudi Arabian Oil Company
InventorPeter Boul
Life of this patent
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Abstract
A precursor cement slurry includes a cement powder, water, and an additive. The additive includes a cement bond enhancer and a non-aqueous fluid additive. The non-aqueous fluid additive is an internal phase and the cement bond enhancer stabilizes the non-aqueous fluid additive in the form of a Pickering emulsion within the precursor cement slurry. The cement bond enhancer is comprised of the reaction product of graphene oxide with an anchoring functionality. A method of forming the precursor cement slurry and a method of cementing an annular space within a wellbore are also provided.
Claims24
A precursor cement slurry, comprising:
- a cement powder;
- water;
- and
- an additive, where the additive includes a cement bond enhancer and a non-aqueous fluid additive;
- where the non-aqueous fluid additive is an internal phase and the cement bond enhancer stabilizes the non-aqueous fluid additive in the form of a Pickering emulsion within the precursor cement slurry, and where the cement bond enhancer is comprised of the reaction product of graphene oxide with an anchoring functionality.
A method of forming a precursor cement slurry, comprising:
- introducing into a cement powder a dry additive that is not a cement bond enhancer such that a dry mixture forms;
- introducing a water-soluble fluid additive and the cement bond enhancer into a water such that a wet suspension forms, where the cement bond enhancer is comprised of the reaction product of graphene oxide with an anchoring functionality;
- introducing a non-aqueous fluid additive into the wet suspension such that a Pickering emulsion forms, where the non-aqueous fluid additive is an internal phase and the cement bond enhancer stabilizes the non-aqueous fluid additive and;
- and
- introducing the dry mixture into the Pickering emulsion such that the precursor cement slurry forms.
A method for cementing an annular space within a wellbore:
- comprising:
- introducing a precursor cement slurry into the wellbore such that it is positioned in the annular space in the wellbore;
- and
- maintaining the wellbore such that the precursor cement slurry cures into a product cement in the annular space,
- where the precursor cement slurry comprises:
- a cement powder;
- water;
- and
- an additive, where the additive includes a cement bond enhancer and a hydrocarbon solvent;
- where the hydrocarbon solvent is an internal phase and the cement bond enhancer stabilizes the hydrocarbon solvent in the form of a Pickering emulsion within the precursor cement slurry and where the cement bond enhancer is comprised of the reaction product of graphene oxide with an anchoring functionality.
Dependencies are inferred from the claim text.