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US 11,732,064 B2Granted
Process for preparing functional polymers through addition of amino and polymeryl groups to aldehyde moieties
OwnerLixin Sun, David D. Devoreinventors
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Abstract
The present disclosure relates to a one-pot process for synthesizing functional compounds or functional polymers by reacting an aldehyde with an alkyl-zinc or polymeryl-zinc composition in the presence of a specific Lewis acid, wherein the reaction is rapid and facile at high temperatures.
Claims12
A process for producing a functional polymer comprising:
- reacting an aldehyde with a zinc composition in the presence of a Lewis acid having the formula (R2N)nMX4-n, wherein
- the zinc composition has the formula ZnR′2 or R1Zn[R′Zn—]YR1, and wherein:
- n is an integer from 1 to 3;
- X is Cl, Br, or I;
- R is a C1-10 hydrocarbon;
- M is a Group 4 metal;
- R′ in each occurrence is a polymer composition;
- R1 in each occurrence is independently selected from a polymer composition, alkyl, hydrogen, halide, amide, hydrocarbyl, hydrocarbylamide, dihydrocarbylamide, hydrocarbyloxide, hydrocarbylsulfide, dihydrocarbylphosphido, tri(hydrocarbyl)silyl;
- any hydrocarbyl group being optionally substituted with at least one halide, amide, hydrocarbylamide, dihydrocarbylamide, or hydrocarbyloxide;
- and each carbon-containing R1 having from 1 to 50 carbon atoms, inclusive;
- and
- Y, on average, in each occurrence is a number from 1-150, inclusive.
9 more elements
Dependencies are inferred from the claim text.