Modification polymerization initiator and method for preparing the same
AssigneeLG Chem, Ltd.
InventorsDong Cheol Choe, Jae Hoon Choe, Hyeon Hui Kim, Jong Young Choi, Jung Yong Lee, Won Jae Lee
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Abstract
The present invention relates to a modification polymerization initiator and a method for preparing the same, and the modification polymerization initiator includes a derived unit from a compound represented by Formula 1 and may include various functional groups in a molecule, and thus, may initiate polymerization reaction and introduce a functional group into a polymer chain at the same time. In addition, the preparation method according to the present invention may prepare the modification polymerization initiator with high purity in high yield.
Claims15
A modification polymerization initiator, comprising at least one derived unit from a compound represented by the following Formula 1 and a derived unit from a compound represented by the following Formula 2:
- in Formula 1,
- A is —NRaRb, —ORc, or —SRd, and
- Ra to Rd are each independently an alkyl group of 1 to 30 carbon atoms, an alkenyl group of 2 to 30 carbon atoms, an alkynyl group of 2 to 30 carbon atoms, a cycloalkyl group of 3 to 30 carbon atoms, an aryl group of 6 to 30 carbon atoms, a heteroalkenyl group of 2 to 30 carbon atoms, a heteroalkynyl group of 2 to 30 carbon atoms, a heterocycloalkyl group of 2 to 30 carbon atoms or a heteroaryl group of 3 to 30 carbon atoms, where each of Ra to Rd is unsubstituted or substituted with a substituent comprising one or more heteroatoms selected among N, O, S, Si and F atoms, and Ra and Rb are optionally combined with each other to form an aliphatic hydrocarbon ring of 5 to 20 carbon atoms, an aromatic hydrocarbon ring of 5 to 20 carbon atoms, or a heterocycle of 3 to 20 carbon atoms, which is unsubstituted or substituted with an alkyl group of 1 to 30 carbon atoms,
- M+—Re− [Formula 2]
- in Formula 2,
- M is an alkali metal, and
- Re is hydrogen, an alkyl group of 1 to 30 carbon atoms, an alkenyl group of 2 to 30 carbon atoms, an alkynyl group of 2 to 30 carbon atoms, a cycloalkyl group of 5 to 30 carbon atoms, or an aryl group of 6 to 30 carbon atoms.
Dependencies are inferred from the claim text.