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US 11,718,714 B2Granted
Polyamides, and methods of producing thereof
AssigneeNovomer, Inc.
InventorsHan Lee, Sadesh H. Sookraj, Alexander Tseitlin
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Abstract
Provided are methods of producing polyamides from beta-lactones. The polyamides include bio-based polyamides that may be obtained, either in part or completely, from renewable sources.
Claims35
A method of producing a polymer, comprising:
- contacting an alkylene oxide and carbon monoxide to form a compound of formula (1);
- combining the compound of formula (1) with a nitrogen-containing compound of formula (2) under aqueous conditions to produce a compound of formula (3-a), wherein:
- the compound formula (1) is
- wherein each R1a, R1b, R1c and R1d is independently H or alkyl,
- the nitrogen-containing compound of formula (2) is R2—NH2, wherein R2 is H or alkyl, and
- combining the compound of formula (3-a) with a weak base to produce the polymer, wherein:
- the compound of formula (3-a) is
- wherein each R1a, R1b, R1c, R1d and R2 is independently H or alkyl, and
- the polymer comprises repeating units of formula
- or a salt thereof wherein each R1a, R1b, R1c, R1d and R2 are as defined above for formula (3-a).
7 more elements
Dependencies are inferred from the claim text.