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AssigneeUmicore AG & Co. KG
InventorsEileen Woerner, Ralf Karch, Andreas Rivas-Nass, Angelino Doppiu
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The invention relates to a method for producing aqueous preparations of complexes of platinum group metals (PGM) Pt, Pd, Rh and Ir having the general formula [MA/MB/MC (L)a (H2O)b (O2−)c(OH−)d](OH—)e(H+)f, wherein MA=PtII or PdII, MB=PtIV, MC=Rh or Ir, L is a neutral monodentate or bidentate donor ligand, and a is an integer between 1 and 4 (or 2) and/or between 1 and 6 (or 3), b is an integer between 0 and 3 (or 5), c is an integer between 0 and 3 (or 4), d is an integer between 0 and 3 (or 5), e is an integer between 0 and 2 (or 3 or 4) and f is an integer between 0 and 4 (or 5). In the method according to the invention, the hydroxo complexes H2Pd(OH)4 (in the case of MA=PdII), H2Pt(OH)6 (in the case of MA=PtII and MB=PtIV) or H3MC(OH)6 (for MC=RhIII IrIII) are converted in the presence of the donor ligands, wherein at least one hydroxo group of the hydro complex is exchanged. Preferably, the reaction occurs at temperatures in the range of 40 to 110° C. with a reaction time of between 2 and 24 hours, wherein, where MA=PtII, the conversion additionally occurs in the presence of a reduction agent. The method optionally further comprises an exchange of OH anions bound outside of the complex sphere with other anions (e.g. hydrogen carbonate or carbonate anions). The aqueous preparations contain PGM complexes such as [Pt(en)2](OH)2, [Pt(EA)4](OH)2 or [Rh(NH3)6](OH)3 and are used to produce electroplating baths, heterogeneous catalysts or metal powders, for example.
A precursor for electroplating baths, for producing heterogeneous catalysts or metal powders or for preparing further complexes comprising water-containing preparations having a pH in the range of 5 to 14 produced by a process producing water-containing preparations of complexes of the platinum group metals (PGM) having the general formula (1), (2) or (3)
Dependencies are inferred from the claim text.