Nickel-plated, heat-treated steel sheet for battery cans
AssigneeToyo Kohan Co., Ltd.
InventorsKota Sadaki, Koh Yoshioka
Life of this patent
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Abstract
The present invention provides a nickel-plated heat-treated steel sheet for a battery can (1), having a nickel layer with a nickel amount of 4.4 to 26.7 g/m2 on a steel sheet (11), wherein when the Fe intensity and the Ni intensity are continuously measured along the depth direction from the surface of the nickel-plated heat-treated steel sheet for a battery can, by using a high frequency glow discharge optical emission spectrometric analyzer, the difference (D2-D1) between the depth (D1) at which the Fe intensity exhibits a first predetermined value and the depth (D2) at which the Ni intensity exhibits a second predetermined value is less than 0.04 μm.
Claims7
A nickel-plated heat-treated steel sheet for a battery can, comprising:
- an iron-nickel diffusion layer formed on a first surface of a steel sheet to be an inner surface of the battery can,
- a first nickel layer constituting an outermost layer with a nickel amount of 4.4 to 26.7 g/m2 on the iron-nickel diffusion layer, and
- a second nickel layer constituting an outermost layer on a second surface of the steel sheet to be an outer surface of the battery can,
- wherein when an Fe intensity and a Ni intensity are continuously measured along a depth direction from the first surface of the nickel-plated heat-treated steel sheet for a battery can, by using a high frequency glow discharge optical emission spectrometric analyzer, a difference (D2-D1) between a depth (D1) at which the Fe intensity exhibits a first predetermined value and a depth (D2) at which the Ni intensity exhibits a second predetermined value is less than 0.04 μm,
- wherein the depth (D1) exhibiting the first predetermined value is the depth exhibiting an intensity of 10% of a saturated value of the Fe intensity measured by the above-described measurement, and
- the depth (D2) exhibiting the second predetermined value is the depth exhibiting an intensity of 10% of a maximum value when the measurement is further performed along the depth direction after the Ni intensity shows the maximum value by the above-described measurement,
- wherein the outermost layer on the iron-nickel diffusion layer consists of nickel and the outermost layer on the second surface of the steel sheet consists of nickel.
A method for producing a nickel-plated heat-treated steel sheet for a battery can, comprising:
- forming a first nickel plating layer on a first surface of a steel sheet to be an inner surface of the battery can with a nickel amount of 4.4 to 26.7 g/m2,
- forming a second nickel plating layer on a second surface of the steel sheet to be an outer surface of the battery can, and
- applying a heat treatment to the steel sheet having the first nickel plating layer and the second nickel plating layer formed thereon by maintaining the steel sheet at a temperature of 350° C. or higher and lower than 450° C. for 30 seconds to 2 minutes so as to form an iron-nickel diffusion layer and a first nickel layer constituting an outermost layer of the first surface, and a second nickel layer constituting an outermost layer of the second surface,
- wherein the outermost layer of the first surface consists of nickel and the outermost layer of the second surface consists of nickel.
Dependencies are inferred from the claim text.