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US 11,699,784 B2Granted
Cathode active material for lithium secondary battery and method of manufacturing the same
AssigneeSK On Co., Ltd.
InventorsJik Soo Kim, Sang Bok Kim, Hyo Shin Kwak, Myoung Lae Kim, Se Rah Moon, Jin Seok Seo, Mi Jung Noh, Duck Chul Hwang
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Abstract
A cathode active material for a lithium secondary battery includes a lithium metal oxide particle and a thio-based compound formed on at least portion of a surface of the lithium metal oxide particle. The thio-based compound has a double bond that contains a sulfur atom. Chemical stability of the lithium metal oxide particle may be improved and surface residues may be reduced by the thio-based compound.
Claims9
A cathode active material for a lithium secondary battery, comprising:
- a lithium metal oxide particle;
- and
- a thio-based compound formed on at least portion of a surface of the lithium metal oxide particle, the thio-based compound including a thioamide compound represented by Structural Formula 1,
- wherein the thio-based compound forms a coating layer, a ligand bond or a complex bond on the surface of the lithium metal oxide particle:
- wherein, in the Structural Formula 1 above, R1 represents hydrogen, halogen, a salt containing O−or S−, a C1-C10 hydrocarbon group capable of substituted with a substituent group, a C1-C10 alkoxy group, an amine group, an amine group substituted with a C1-C10 alkyl group, a C1-C10 thioalkyl group or a thioamide group,
- wherein R2 and R3 are each independently hydrogen or a C1-C10 hydrocarbon group capable of substituted with a substituent group, R2 and R3 are capable of being fused together to form a ring, and
- wherein the substituent group capable of being combined with R1, R2 and R3 includes halogen, a cyano group, a hydroxyl group or a carboxyl group.
4 more elements
Dependencies are inferred from the claim text.